Saturday, 06 August 2011 03:31

Aromatic Amino Compounds: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

4-AMINODIPHENYL         92-67-1

eyes; bladder

Inhalation: dullness, headache

Skin: may be absorbed

Eyes: redness

Bladder; skin (bladder cancer)Inh; abs; ing; con

Head, dizz; leth, dysp; ataxia, weak; methemo; urinary burning; acute hemorrhagic cystitis; (carc)

o-AMINOPHENOL            95-55-6

blood

skin

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, unconsciousness, symptoms may be delayed

Eyes: Redness

ANILINE            62-53-3

eyes; blood; CNS

liver; kidneys; spleen; skin; blood

Inhalation: blue lips or finger nails, blue skin, headache, dizziness, laboured breathing, convulsions, increased heartbeat, vomiting, weakness, unconsciousness

Skin: may be absorbed

Eyes: redness

Blood; CVS; eyes; liver; kidneys; resp sys  (in animals: tumors of the spleen) Inh; abs; ing; con

Head, weak, dizz; cyan; ataxia; dysp on effort; tacar; irrit eyes; methemo; cirr; (carc)

ANILINE HYDROCHLORIDE     142-04-1

eyes; skin; resp tract; blood

skin; spleen; kidneys; blood

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, nausea, shortness of breath, sore throat, unconsciousness, vomiting, weakness

Skin: may be absorbed, redness

Eyes: redness, pain

Ingestion: abdominal pain

o-ANISIDINE      90-04-0

blood

blood

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, nausea, vomiting

Skin: may be absorbed

Blood; kidneys; liver; CVS; CNSInh; abs; ing; con

Head, dizz; cyan; RBC Heinz bodies; (carc)

p-ANISIDINE      104-94-9

blood

blood

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, laboured breathing, nausea, vomiting

Skin: may be absorbed, blue lips or fingernails, blue skin

Ingestion: blue lips or fingernails, blue skin

Blood; kidneys; liver; CVS; CNSInh; abs; ing; con

Head, dizz; cyan; RBC Heinz bodies; (carc)

BENZIDINE        92-87-5

Bladder; kidneys; liver; skin; blood  (liver, kidney and bladder cancer) Inh; abs; ing; con

Hema; secondary anemia from hemolysis; acute cystitis; acute liver disorders; derm;  painful, irreg urination; (carc)

o-CHLOROANILINE         95-51-2

eyes; skin

skin; liver; kidneys; blood

Inhalation: blue lips or finger nails, blue skin, convulsions, diarrhoea, dizziness, headache, nausea, shortness of breath, vomiting, weakness

Skin: may be absorbed, redness

Eyes: redness, pain

Ingestion: abdominal pain

m-CHLOROANILINE         108-42-9

eyes; skin; resp tract; liver; kidneys

blood

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, nausea, shortness of breath, unconsciousness

Skin: may be absorbed, redness, burning sensation

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain,

p-CHLOROANILINE         106-47-8

eyes; skin; resp tract; blood

skin ; blood; liver; kidneys; spleen ; bone marrow

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing

Skin: may be absorbed, redness

Eyes: redness, pain

Ingestion: nausea

2,4-DIAMINOTOLUENE    95-80-7

eyes; skin; resp tract; lungs; heart; liver; blood

skin

Inhalation: blue lips or finger nails, blue skin, dizziness, increased heart rate, laboured breathing, nausea, vomiting, convulsions, respiratory depression

Skin: may be absorbed, redness on contact with molten material - skin burns, blisters

Eyes: redness

Ingestion: abdominal pain, blue skin, headache, nausea, vomiting

Eyes, skin, resp sys, blood, CVS, liver, CNS  (in animals: liver, skin & mammary gland tumors) Inh; abs; ing; con

Irrit eyes, skin, nose, throat; derm; ataxia, tacar, nau, vomit, convuls, resp depres; methemo, cyan, head, ftg, dizz, bluish skin; liver inj; (carc)

2,6-DIAMINOTOLUENE    823-40-5

eyes; skin; resp tract; blood

skin

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, shortness of breath

Skin: redness

Eyes: redness, pain

Ingestion: laboured breathing

2,3-DICHLOROANILINE    608-27-5

liver; kidneys

skin ; blood

Inhalation: blue lips or finger nails, blue skin, convulsions, diarrhoea, dizziness, headache, shortness of breath, vomiting, weakness

Skin: may be absorbed, redness

Eyes: redness, pain

2,4-DICHLOROANILINE    554-00-7

liver; kidneys

skin ; blood

Inhalation: blue skin, dizziness, headache, shortness of breath

Skin: may be absorbed, redness, skin burns

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain, nausea

2,5-DICHLOROANILINE    95-82-9

liver; kidneys

skin ; blood

Inhalation: blue skin, dizziness, headache, shortness of breath

Skin: may be absorbed, redness, skin burns

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain, nausea

2,6-DICHLOROANILINE    608-31-1

liver; kidneys

skin ; blood

Inhalation: blue skin, dizziness, headache, shortness of breath

Skin: may be absorbed, redness

Eyes: redness, pain

3,4-DICHLOROANILINE    95-76-1

liver; kidneys

skin; blood

Inhalation: blue skin, dizziness, headache, shortness of breath

Skin: may be absorbed, redness, burning sensation

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain, nausea

3,3'-DICHLOROBENZIDINE     91-94-1

resp tract

skin; liver

Inhalation: cough, sore throat

Skin: may be absorbed

Bladder; liver; lung ; skin; GI tract  (in animals: liver & bladder cancer) Inh; abs; ing; con

Skin sens, derm; head, dizz; caustic burns; frequent urination, dysuria; hema; GI upset; upper resp infection; (carc)

DIMETHYLANILINE          121-69-7

blood

skin

Inhalation: abdominal pain, blue skin, dizziness, headache, ringing in the ears, laboured breathing, unconsciousness, vomiting, visual disturbance

Skin: may be absorbed, redness

Eyes: redness, pain

Blood; kidneys;liver; CVSInh; abs; ing; con

Anoxia US NIOSH Symptoms; cyan, weak, dizz, ataxia; methemo

DIMETHYLAMINOAZOBENZENE     60-11-7

Skin; resp sys; liver; kidneys; bladder ( in animals: liver & bladder tumors) Inh; abs; ing; con

Enlarged liver; liver, kidney dysfunc; contact derm; cough, wheez, dysp; bloody sputum; bronchial secretions; frequent urination, hema, dysuria; (carc)

N,N-DIMETHYL-p-TOLUIDINE     99-97-8

blood; brain; kidneys

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, shortness of breath, weakness

Skin: may be absorbed

2,4-DINITROANILINE       97-02-9

eyes; skin; resp tract; blood

blood

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, nausea, sore throat

Skin: may be absorbed, redness, blue lips or fingernails, blue skin

Eyes: redness, pain

Ingestion: unconsciousness

DIPHENYLAMINE            122-39-4

eyes; skin; resp tract

kidneys

Inhalation: cough, sore throat

Skin: redness

Eyes: redness

Eyes; skin; resp sys; CVS; blood; bladder; repro sysInh; abs; ing; con

Irrit eyes, skin muc memb; eczema; tacar, hypertension; cough, sneez; methemo; incr BP, heart rate; prot, hema, bladder inj; in animals: terato effects

N-ISOPROPYLANILINE    768-52-5

skin; blood; brain; kidneys

skin ; blood

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing

Skin: may be absorbed, blue lips or fingernails, blue skin

Eyes: redness, pain, blurred vision

Ingestion: nausea

Eyes; skin; resp sys; blood; CVS; liver; kidneysInh; abs; ing; con

Irrit eyes, skin; head, weak, dizz; cyan; ataxia; dysp on effort; tacar; methemo

N-ISOPROPYL-N'-PHENYL-p-­PHENYLENEDIAMINE      101-72-4

eyes; skin

skin

Inhalation: cough, irritant

Skin: redness, irritant

Eyes: redness, irritant

METHYLANILINE 100-61-8

eyes; skin; resp tract; blood; brain; kidneys

skin; blood

Inhalation: blue lips or finger nails, blue skin, cough, dizziness, headache, laboured breathing, sore throat

Skin: may be absorbed, redness, pain

Eyes: redness, pain, blurred vision

Ingestion: abdominal pain, blue lips or fingernails, blue skin, dizziness, headache, laboured breathing, nausea

Resp sys; liver; kidneys; blood; CNSInh; abs; ing; con

Weak, dizz, head; dysp, cyan; methemo; pulm edema; liver, kidney damage

1,5-NAPHTHALENEDIAMINE     2243-62-1

skin

Skin: may be absorbed

a-NAPHTHYLAMINE        134-32-7

Bladder; skin  (bladder cancer) Inh; abs; ing; con

Derm; hemorrhagic cystitis; dysp, ataxia, methemo; hema; dysuria; (carc)

b-NAPHTHYLAMINE         91-59-8

Bladder; skin  (bladder cancer) Inh; abs; ing; con

Derm; hemorrhagic cystitis; dysp; ataxia; methemo, hema; dysuria; (carc)

o-NITROANILINE 88-74-4

blood

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, laboured breathing, nausea, shortness of breath, unconsciousness, weakness

Skin: may be absorbed, blue lips or fingernails, blue skin

m-NITROANILINE            99-09-2

blood

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, laboured breathing, nausea, shortness of breath, unconsciousness, weakness

Skin: may be absorbed, blue lips or fingernails, blue skin

p-NITROANILINE 100-01-6

blood

liver

Inhalation: blue lips or finger nails, blue skin, dizziness, drowsiness, headache, laboured breathing, nausea, shortness of breath, unconsciousness, weakness

Skin: may be absorbed, blue lips or fingernails, blue skin

Resp sys; blood; heart; liver; ­abs; ing; con

Irrit nose, throat; cyan, ataxia; tacar, tachypnea; dysp; irrity; vomit, diarr; convuls; resp arrest; anemia; methemo; jaundice

N-PHENYL-1-NAPHTHYLAMINE     90-30-2

skin

Skin: redness

p-PHENYLENEDIAMINE   106-50-3

resp tract; blood; kidneys

skin; resp tract

Inhalation: cough, dizziness, headache, laboured breathing

Skin: redness

Eyes: redness, blurred vision, even permanent loss of vision

Ingestion: abdominal pain, blue lips or fingernails, blue skin, vomiting, weakness, convulsions, coma, death

Resp sys ; skinInh; abs; ing; con

Irrit pharynx, larynx; bronchial asthma; sens derm

p-PHENYLENEDIAMINE HYDROCHLORIDE           624-18-0

eyes; skin; resp tract; blood; brain; kidneys

skin; resp tract; liver

Inhalation: cough, dizziness, laboured breathing, see ingestion

Skin: redness

Eyes: blurred vision, even permanent loss of vision

Ingestion: abdominal pain, blue lips or fingernails, blue skin, vomiting, weakness, swelling of the face and neck, convulsions, coma, death

o-TOLIDINE        119-93-7

eyes; skin; resp tract

skin; blood

Inhalation: cough, weak irritant

Skin: may be absorbed

Eyes; resp sys; liver; kidneys; (in animals: liver, bladder & mammary gland tumors)Inh; abs; ing; con

Irrit eyes, nose; in animals: liver, kidney damage; (carc)

o-TOLUIDINE      95-53-4

Eyes; skin; blood; kidneys; liver; CVS  (in animals: liver, bladder & mammary gland tumors) Inh; abs; ing; con

Irrit eyes; anoxia, head, cyan; weak, dizz, drow; micro hema, eye burns; derm;  (carc)

XYLIDINE          1300-73-8

eyes; skin; resp tract; blood

kidneys; liver; red blood cells

Inhalation: blue lips or finger nails, blue skin, dizziness, headache, laboured breathing

Skin: may be absorbed

Eyes: redness, pain, blurred vision

Ingestion: blue lips or fingernails, blue skin, dizziness, headache

Resp sys; blood; liver; kidneys; CVSInh; abs; ing; con

Anoxia, cyan, methemo; lung, liver, kidney damage

 

Back

Chemical Formula

Chemical

Synonyms
UN code

CAS-Number

120661

o-ACETOTOLUIDINE

Acetamide, acetyl-o-toluidine;
o-Methylacetanilide;
2-Methylacetanilide;
2'-Methylacetanilide;
N-(2-methylphenyl)acetamide

120-66-1

82280

1-AMINO-2-METHYLANTHRAQUINONE

Acetate fast orange R;
Acetoquinone light orange JL;
1-Amino-2-methyl-9,10-anthracenedione

82-28-0

92671

4-AMINODIPHENYL

p-Aminobiphenyl;
4-Aminobiphenyl;
p-Aminodiphenyl;
Biphenylamine

92-67-1

95556

o-AMINOPHENOL

2-Amino-1-hydroxybenzene;
2-Aminophenol;
o-Hydroxyaniline;
2-Hydroxyanaline;
Nako yellow 3GA
UN2512

95-55-6

123308

p-AMINOPHENOL

4-Amino-1-hydroxybenzene;
4-Aminophenol;
Azol;
BASF Ursol P base;
p-Hydroxyaniline;
4-Hydroxyaniline
UN2512

123-30-8

62533

ANILINE

Aminobenzene;
Benzenamine;
Phenylamine
UN1547

62-53-3

142041

ANILINE HYDROCHLORIDE

Aniline chloride;
Hydrochloride benzenamide;
Phenylamine hydrochloride
UN1548

142-04-1

90040

o-ANISIDINE

o-Aminoanisole;
2-Aminoanisole;
1-Amino-2-methoxybenzene;
2-Anisidine;
2-Methoxy-1-aminobenzene;
Methoxyphenylamine

90-04-0

104949

p-ANISIDINE

p-Aminoanisole;
4-Aminoanisole;
1-Amino-4-methoxybenzene;
4-Anisidine;
4-Methoxy-1-aminobenzene;
Methoxybenzenamine

104-94-9

134292

o-ANISIDINE HYDROCHLORIDE

2-Aminoanisole hydrochloride;
o-Aminoanisole hydrochloride ;
o-Anisylamine hydrochloride;
C.I. 37115;
Fast red BB base;
2-Methoxy-1-aminobenzene hydrochloride;
o-Methoxyaniline hydrochloride;
2-Methoxyaniline hydrochloride

134-29-2

492808

AURAMINE

Bis(p-dimethylaminophenyl)methylene­imine;
Brilliant oil yellow;
4,4'-Carbonimidoylbis­(N,N-Dimethylbenzenamine);
C.I. 41000B;
C.I. basic yellow;
2, 4,4'-dDmethylaminobenzo­phenonimide;
Glauramine

492-80-8

92875

BENZIDINE

4,4'-Bianiline;
4,4'-Biphenyldiamine;
C.I. 37225;
C.I. Azoic diazo component 112;
4,4'-Diaminobiphenyl;
4,4'-Diaminodiphenyl;
4,4'-Diphenylenediamine
UN1885

92-87-5

591195

m-BROMOANILINE

591-19-5

106401

p-BROMOANILINE

4-Bromobenzenamine;
p-Bromophenylamine

106-40-1

121879

2-CHLORO-4-NITROANILINE

1-Amino-2-chloro-4-nitrobenzene;
o-Chloro-p-nitroaniline;
4-Nitro-2-chloroaniline

121-87-9

95830

4-CHLORO-o-PHENYLENEDIAMINE

2-Amino-4-chloroaniline;
C.I. 76015;
4-Chloro-1,2-benzenediamine;
4-Chloro-1,2-diaminobenzene;
4-Chloro-1,2-phenylenediamine;
1,2-Diamino -4-chlorobenzene;
3,4-Diaminochlorobenzene;
3,4-Diamino-1-chlorobenzene

95-83-0

95692

4-CHLORO-o-TOLUIDINE

2-Amino-5-chlorotoluene;
Azogene fast red TR;
3-Chloro-6-aminotoluene;
5-Chloro-2-aminotoluene;
4-Chloro-2-methylaniline;
4-Chloro-6-methylaniline;
2-Methyl-4-chloroaniline

95-69-2

95794

5-CHLORO-o-TOLUIDINE

2H-1-Benzopyran-2-one;
2H-1-Benzopyran, 2-Oxo-;
Benzo-a-pyrone;
1,2-Benzopyrone;
Cinnamic acid, o-Hydroxy-, d-lactone;
cis-o-Coumarinic acid lactone;
Coumarinic anhydride;
Cumarin;
o-Hydroxycinnamic acid lactone;
o-Hydroxycinnamic lactone;
NCI C07103;
2-Oxo-1,2-benzopyran;
Rattex;
Tonka bean camphor

95-79-4

95512

o-CHLOROANILINE

1-Amino-2-Chlorobenzene;
2-Chloroaniline;
2-Chlorobenzenamine

95-51-2

108429

m-CHLOROANILINE

m-Aminochlorobenzene;
1-Amino-3-Chlorobenzene;
3-Chloroaniline;
3-Chlorobenzenamine

108-42-9

106478

p-CHLOROANILINE

1-Amino-4-chlorobenzene;
4-Chlorobenzenamine;
4-Chlorophenylamine

106-47-8

120718

p-CRESIDINE

3-Amino-p-cresol methyl ether;
1-Amino-2-methoxy-5-methylbenzene;
3-Amino-4-methoxytoluene;
2-Amino-4-methylanisole;
5-Methyl-o-anisidine;
Azoic red 36

120-71-8

93469

N,N'-DI-2-NAPHTHYL-p-PHENYLENE­DIAMINE

Aceto DIPP;
Agerite white;
N,N'-Bis(2-naphthyl)-p-phenylene­diamine;
Di-b-naphthyl-p-phenylenediamine;
N,N'-Di-b-naphthyl-p-phenylenediamine;
DNPD;
DNPDA

93-46-9

615054

2,4-DIAMINOANISOLE

C.I. 76050;
M-Diaminoanisole 1,3-diamino-4-methoxybenzene;
2,4-Diamino-1-methoxybenzene;
Furro l;
4-Methoxy-1,3-benzenediamine

615-05-4

91952

3,3'-DIAMINOBENZIDINE

3,3',4,4'-Biphenyltetramine ;
3,3',4,4'-Diphenyltetramine;
3,3',4,4'-Tetraaminobiphenyl

91-95-2

137097

2,4-DIAMINOPHENOL DIHYDROCHLORIDE

Acrol;
amidol;
2,4-Diaminophenol hydrochloride;
Dianol;
NCI-C60026

137-09-7

95807

2,4-DIAMINOTOLUENE

3-Amino-p-toluidine;
5-Amino-o-toluidine;
Azogen developer Hh;
Benzofur MT;
C.I. 76035;
1,3-Diamino-4-methylbenzene;
2,4-Siamino-1-methylbenzene
UN1709

95-80-7

823405

2,6-DIAMINOTOLUENE

1,3-Benzenediamine, 2-Methyl-;
2,6-toluylenediamine;
2,6-Tolylenediamine

823-40-5

613296

N,N-DIBUTYLANILINE

613-29-6

608275

2,3-DICHLOROANILINE

608-27-5

554007

2,4-DICHLOROANILINE

Benzenamine, 2,4-Dichloro-

554-00-7

95829

2,5-DICHLOROANILINE

95-82-9

608311

2,6-DICHLOROANILINE

608-31-1

95761

3,4-DICHLOROANILINE

1-Amino-3,4-Dichlorobenzene;
4,5-Dichloroaniline;
3,4-Dichlorobenzenamine

95-76-1

91941

3,3'-DICHLOROBENZIDINE

C.I. 23060;
Curithane C126;
DCB;
4,4'-Diamino-3,3'-dichlorobiphenyl;
Dichlorobenzidine;
3,3'-Dichloro-4,4'-biphenyldiamine

91-94-1

612839

3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE

(1,1'-Biphenyl)-4,4'-diamine, 3,3'-Dichloro-, dihydrochloride

612-83-9

3129917

DICYCLOHEXYLAMINONITRITE

N-Cyclohexylcyclohexanamine nitrite;
Dechan;
Diana;
Dicyclohexylammonium nitrite
UN2687

3129-91-7

91689

m-DIETHYLAMINOPHENOL

3-(Diethylamino)phenol

91-68-9

91667

N,N-DIETHYLANILINE

N,N-Diethylaminobenzene;
Diethylaniline;
N,N-Diethylbenzenamine;
Diethylphenylamine
UN2432

91-66-7

20325400

3,3'-DIMETHOXYBENZIDINE DIHYDROCHLORIDE

o-Dianisidine dihydrochloride;
3,3'-Dimethoxy-4,4'-Diaminobiphenyl dihydrochloride;
3,3'-Dimethoxy-(1,1-biphenyl)-­4,4'-diamine dihydrochloride

20325-40-0

99978

N,N-DIMETHYL-p-TOLUIDINE

Benzenamine, N,N,4-Trimethyl-;
N,N,4-Trimethylaniline;
p-N,N-Trimethylaniline

99-97-8

60117

DIMETHYLAMINOAZOBENZENE

p-Dimethylaminoazobenzene;
N,N-Dimethyl-4-aminoazobenzene, Benzeneazodimethylaniline, 4-Dimethylaminoazobenzene,4-­Dimethylaminoazobenzol;
DAB

60-11-7

121697

DIMETHYLANILINE

Dimethylaminobenzene;
N,N-Dimethylbenzenamidne;
Dimethylphenylamine
UN2253

121-69-7

97029

2,4-DINITROANILINE

2,4-Dinitraniline;
2,4-Dinitrobenzenamine

97-02-9

74317

N,N'-DIPHENYL-p-PHENYLENEDIAMINE

Agerite;
Agerite DPPD;
1,4-Bis(phenylamino)benzene;
Diphenyl-p-phenylenediamine;
DPPD;
Flexamine g;
JZF;
Nonox DPPD

74-31-7

122394

DIPHENYLAMINE

Anilinobenzene;
benzene C.I. 10355;
No scald;
No scald DPA 283;
N-Phenylaniline;
N-Phenylbenzenamine

122-39-4

102067

1,3-DIPHENYLGUANIDINE

Diphenylguanidine;
N,N'-Diphenylguanidine

102-06-7

103695

N-ETHYLANILINE

Anilinoethane;
N-Ethylaminobenzene;
Ethylaniline;
N-Ethylbenzenamine;
Ethylphenylamine
UN2272

103-69-5

101724

N-ISOPROPYL-N'-PHENYL-p-PHENYL­ENEDIAMINE

Cyzone;
Elastozone 34;
Flexzone 3c;
4-Isopropylaminodiphenylamine;
N-Phenyl-N'-isopropyl-p-phenylene­diamine;
N-2-propyl-N'-phenyl-p-phenylene­diamine;
Santoflex 36

101-72-4

76852

N-ISOPROPYLANILINE

768-52-5

108781

MELANINE

Aero;
Ammelide;
Cyanuramide;
Cyanuric triamide;
4,6-Triamino-1,3,5-Triazine;
1,3,5-Triazine-2,4,6-triamine

108-78-1

150754

p-METHYLAMINOPHENOL

4-(Methylamino)phenol

150-75-4

100618

METHYLANILINE

Anilinomethane;
(Methylamino)benzene;
Methylphenylamine;
Monomethylaniline
UN2294

100-61-8

101144

4,4’-METHYLENE-BIS CHLOROANILINE

Bis-amine;
Bis-amine A;
Bisamine S;
Bis(4-amino-3-chlorophenyl)methane;
Bis(3-chloro-4-aminophenyl)methane;
CL-MDA;
Buamine M;
MBOCA;
MOCA

101-14-4

838880

4,4'-METHYLENEBIS(2-METHYLANILINE)

Bis(4-amino-3-methylphenyl)methane;
3,3'-Dimethyl-4,4'-diaminodiphenyl­methane;
MBOT;
Me-MDA;
4,4'-Methylenebis(2-methylbenzenamine)

838-88-0

1208522

2,4'-METHYLENEDIANILINE

2',4-Bis(aminophenyl)methane;
o,p'-Diaminodiphenylmethane;
2,4'-Diaminodiphenylmethane;
2,4'-Diphenylmethanediamine

1208-52-2

101779

4,4-METHYLENEDIANILINE

Ancamine tl;
Araldite hardener 972;
Bis(p-aminophenyl)methane;
Bis(4-aminophenyl)methane;
Curithane;
DADPM;
DAPM;
DDM;
Diaminodiphenylmethane;
Dianilinomethane;
4,4'-Diphenylmethanediamine
UN2651

101-77-9

101611

MICHLER'S BASE

4,4'-Bis(dimethylamino)diphenylmethane;
Bis(p-dimethylaminophenyl)methane;
Michler's methane;
Reduced Michler's ketone;
Tetramethyldiaminodiphenylmethane

101-61-1

90948

MICHLER'S KETONE

Bis(p-(N,N-dimethylamino)phenyl)ketone;
Bis(4-(dimethylamino)phenyl)methanone;
4,4'-Bis(dimethylamino)benzophenone;
Tetramethyldiaminobenzophenone

90-94-8

2243621

1,5-NAPHTHALENEDIAMINE

1,5-Diaminonaphthalene;
1,5-Naphthylenediamine;
NCI-C03021

2243-62-1

134327

a-NAPHTHYLAMINE

1-Naphthylamine;
1-Aminonaphthalene;
C.I. Azoic diazo component 114;
Naphthalidam;
Naphthalidine
UN2077

134-32-7

91598

b-NAPHTHYLAMINE

2-Aminonaphthalene;
C.I. 37270;
Fast scarlet base B;
2-Naphthylamine;
2-Naphthalenamine;
6-Naphthylamine
UN1650

91-59-8

88744

o-NITROANILINE

1-Amino-2-nitrobenzene;
2-Nitroaniline
UN1661

88-74-4

99092

m-NITROANILINE

1-Amino-3-nitrobenzene;
Nitranilin;
m-Nitroaniline;
3-Nitroaniline;
3-Nitrobenzenamine
UN1661

99-09-2

100016

p-NITROANILINE

p-Aminonitrobenzene;
1-Amino-4-nitrobenzene;
4-Nitroaniline;
4-Nitrobenzenamine
UN1661

100-01-6

138896

p-NITROSO-N,N-DIMETHYLANILINE

138-89-6

101804

4,4'-OXYDIANILINE

4-Aminophenyl ether;
Diaminodiphenyl ether;
4,4'-Diaminophenyl oxide;
4,4'-Oxybisaniline;
4,4'-Oxybisbenzenamine

101-80-4

90302

N-PHENYL-1-NAPHTHYLAMINE

1-Anilinonaphthalene;
Phenylnaphthylamine;
Phenyl-a-naphthylamine

90-30-2

135886

N-PHENYL-b-NAPHTHYLAMINE

Anilinonaphthalene;
2-Anilinonaphthalene;
N-(2-Naphthyl)aniline;
Phenylaminonaphthalene

135-88-6

1477550

m-PHENYLENEBIS(METHYLAMINE)

1,3-Bis(aminomethyl)benzene;
MXDA;
m-Xylene-a,a'-Diamine;
m-Xylylenediamine

1477-55-0

95545

o-PHENYLENEDIAMINE

2-Aminoaniline;
o-Benzenediamine;
1,2-Benzenediamine;
C.I. 76010;
C.I. oxidation base 16;
o-Diaminobenzene;
1,2-Diaminobenzene;
o-Phenylenediamine;
1,2-Phenylenediamine
UN1673

95-54-5

108452

m-PHENYLENEDIAMINE

m-Aminoaline;
3-Aminoaniline;
m-Benzenediamine;
1,3-Benzenediamine;
C.I. 76025;
Developer 11;
m-Diaminobenzene;
1,3-diaminobenzene;
m-Phenylenediamine;
Metaphenylenediamine;
1,3-Phenylenediamine
UN1673

108-45-2

106503

p-PHENYLENEDIAMINE

p-Aminoaniline;
4-Aminoaniline;
p-Benzenediamine;
1,4-Benzenediamine;
Benzofur D;
C.I. 76060;
Pelagol D
UN1673

106-50-3

624180

p-PHENYLENEDIAMINE HYDROCHLORIDE

p-Aminoaniline dihydrochloride;
4-Aminoaniline dihydrochloride;
p-Benzenediamine dihydrochloride;
1,4-Benzenediamine dihydrochloride;
C.I. 76061;
C.I. oxidation base 10A;
p-Diaminobenzene dihydrochloride;
1,4-Diaminobenzene dihydrochloride

624-18-0

122985

N-PHENYLETHANOLAMINE

Aniline, N-(2-hydroxyethyl)-;
2-(Phenylamino)ethanol;
N-Phenylethanolamine

122-98-5

119937

o-TOLIDINE

Bianisidine;
(1,1'-Biphenyl)-4,4'-diamine-3,3'-Dimethyl-;
4,4'-bi-o-toluidine;
C.I. 37230;
C.I. Azoic diazo component 113;
4,4'-Diamino-3,3'-dimethylbiphenyl;
4,4'-Diamino-3,3'-dimethyldiphenyl;
3,3'-Dimethylbenzidin

119-93-7

95534

o-TOLUIDINE

1-Amino-2-methylbenzene;
o-aminotoluene;
2-Aminotoluene;
C.I. 37077;
1-Methyl-2-aminobenzene;
o-Methylaniline
UN1708

95-53-4

108441

m-TOLUIDINE

3-Amino-1-methylbenzene;
3-Aminophenylmethane;
m-Aminotoluene;
3-Aminotoluene;
m-Methylaniline;
3-Methylaniline
UN1708

108-44-1

106490

p-TOLUIDINE

4-Amino-1-methylbenzene;
p-Aminotoluene;
4-Aminotoluene;
C.I. 37107;
C.I. Azoic coupling component 107;
p-Methylaniline;
4-Methylaniline;
p-Methylbenzenamine;
4-Methylbenzenamine
UN1708

106-49-0

137177

2,4,5-TRIMETHYLANILINE

1-Amino-2,4,5-trimethylbenzene;
1,2,4-Trimethyl-5-Aminobenzene;
2,4,5-Trimethylaniline

137-17-7

603349

TRIPHENYLAMINE

N,N-Diphenylaniline;
N,N-Diphenylbenzenamine

603-34-9

1300738

XYLIDINE

Acid leather brown 2G;
Acid orange 24;
Aminodimethylbenzene;
Dimethylaminobenzene;
Dimethylaniline;
Dimethylphenylamine
UN1711

1300-73-8

87592

2,3-XYLIDINE

2,3-Dimethylaniline;
2,3-Dimethylbenzenamine;
2,3-Dimethylphenylamine;
o-Xylidine;
2,3-Xylylamine

87-59-2

95681

2,4-XYLIDINE

1-Amino-2,4-dimethylbenzene;
4-Amino-1,3-Dimethylbenzene;
4-Amino-3-methyltoluene;
4-Amino-1,3-xylene;
2,4-Dimethylaniline;
2,4-Dimethylbenzenamine

95-68-1

95647

3,4-XYLIDINE

3,4-Dimethylaminobenzene;
3,4-Dimethylaniline;
3,4-Dimethylbenzenamine;
3,4-Dimethylphenylamine;
3,4-Xylylamine

95-64-7

 

Back

Chemical Name

CAS-Number

Colour/Form

Boiling Point (ºC)

Melting Point (ºC)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (ºC)

Auto Ignition Point (ºC)

ACETALDEHYDE-OXIME
107-29-9

needles; two crystalline modifications

115

47

59.07

sol

0.9656

@ 25.8 ºC

<22

ALLYLAMINE
107-11-9

colourless to light yellow liquid

55-58

-88

57.09

misc

0.76

2.0

26.4

2.2 ll
22 ul

-29 cc

370

BUTYLAMINE
109-73-9

clear, colourless liquid

77.8

-50

73.1

misc

0.7414

2.5

10.9

1.7 ll
9.80 ul

-1 oc

312

sec-BUTYLAMINE
13952-84-6

colourless liquid

63

-104

73.14

misc

0.724

2.52

18

1.7 ll
9.8 ul

- 9

378

tert-BUTYLAMINE
75-64-9

colourless liquid

44

-72.65

73.1

misc

0.6951

2.5

@ 25 ºC.

1.7 ll
8.9 ul

10

380

CYCLOHEXYLAMINE
108-91-8

colourless to yellow liquid

134

-17.7

99.17

sol

0.8191

3.42

1.2

1.5 ll
9.4 ul

31 cc

293

DIALLYLAMINE
124-02-7

liquid

111

-88.4

97.2

8.6 g/ 100 ml

@ 10 ºC/4 ºC

3.35

2.4

21

1,3-BUTANEDIAMINE
590-88-5

water white liquid

143-150

0.858

516

1,5-PENTANEDIAMINE
462-94-2

179

9

102.17

sol

0.873 25 ºC

1,3-PROPANEDIAMINE
109-76-2

140

74.12

sol

0.884

DIBUTYLAMINE
111-92-2

liquid; colourless

160

-60-59

129.24

sol

0.7670

4.46

1.9 mm Hg

1.1

57 oc

2,2'-DICHLORO-N-­METHYLDIETHYLAMINE
51-75-2

mobile liquid

@ 18 mm Hg

-60

156.07

sl sol

@ 25 ºC/4 ºC

DICYCLOHEXYLAMINE
101-83-7

colourless liquid

256

-0.1

181.31

sl sol

0.9123

6.25

110

DIETHANOLAMINE
111-42-2

prisms; usually offered as a viscous liquid; crystalline solid

268.8

28

105.1

v sol

1.0966

3.65

< 0.001

134 oc

660

DIETHYLAMINE
109-89-7

colourless liquid

55.5

-49.8

73.1

v sol

0.71

2.53

25.9

1.8 ll
10.1. ul

-26 cc

312

2-DIETHYLAMINO­ETHANOL
100-37-8

colourless liquid

163

-70

117.19

misc

0.8921

4.03

0.19

6.7 ll
11.7 ul

52 cc

250

DIETHYLENETRIAMINE
111-40-0

yellow liquid

207

-39

103.2

misc

0.96

3.56

0.037

1 ll
10 ul

97-102 oc

390-395

DIISOPROPYLAMINE
108-18-9

colourless liquid

84

-61

101.19

sl sol

0.7169

3.5

8.0

0.8 ll
7.1 ul

-1 oc

316

DIMETHYLAMINE
124-40-3

gas at ordinary temperature; colourless gas

7

-92

45.08

v sol

0.680

1.6

206

2.8 ll
14.4 ul

402

DIMETHYLAMINE HYDROCHLORIDE
506-59-2

171

81.54

v sol

3-DIMETHYLAMINO­PROPYLAMINE
109-55-7

colourless liquid

123

-70

102.2

sol

@ 30 ºC

3.5

DIMETHYLETHANOL­AMINE
108-01-0

colourless liquid

135

-59

89.1

misc

0.8866

3.03

560

41oc

220

3,3'-DIAMINODIPRO­PYLAMINE
56-18-8

@ 50 ºC

-14

131.22

@ 25 ºC

ETHANOLAMINE
141-43-5

viscous, clear, hydroscopic fluid; viscous liquid

171

10.5

61.08

misc

1.0180

2.1

@ 25 ºC

85 cc

410

ETHYLAMINE
75-04-7

colourless liquid or gas

17

-81

45.08

misc

@ 15 ºC/15 ºC

1.55

121

3.5 ll
14 ul

-17 cc

725

ETHYLENEDIAMINE
107-15-3

colourless liquid; water-white liquid

117

8.5

60.10

v sol

0.8979

2.07

1.2

4.2 ll
14.4 ul

34 cc

385

ETHYLENIMINE
151-56-4

colourless, mobile fluid; oil

56-57

-71.5

43.08

sol

@ 24 ºC/4 ºC

1.48

21.3

3.6 ll
46 ul

11 cc

322

2-ETHYLHEXYLAMINE
104-75-6

colourless liquid

129.24

sol

1.2

60 oc

HEXAMETHYLENE­DIAMINE
124-09-4

colourless leaflets; rhombic bipyramidal plates

205

42

116.20

v sol

0.93

4.01

@ 50 ºC

0.7 ll
6.3 ul

71

310

HYDROXYETHYL ETHYLENEDIAMINE
111-41-1

colourless liquid

238-40

104.15

misc

1.0286

3.59

@ 25 ºC

135 cc

ISOBUTANOLAMINE
124-68-5

crystalline mass

165

31

89.1

misc

0.934

3.0

67 cc

ISOBUTYLAMINE
78-81-9

colourless liquid

68

-85

73.1

v sol

@ 25 ºC/4 ºC

2.5

@ 18.8 ºC

3.4 ll
9 ul

378

ISOPHORONE DIAMINE
2855-13-2

colourless liquid

247

10

170.30

v sol

0.92

2 Pa

110

ISOPROPANOLAMINE
78-96-6

liquid

159.46

1.74

75.11

sol

0.9611

2.6

< 0.2

77

374

ISOPROPYLAMINE
75-31-0

colourless liquid

33-34

-101

59.1

misc

@ 15 ºC/4 ºC

2.04

@ 25 ºC

2.3 ll
12 ul

-37 oc

402

HEXAMETHYLENE­TETRAMINE
100-97-0

rhombic crystals from alcohol; crystals or granules or powder; colourless, lustrous crystals or white crystalline powder

140.19

1 g /1.5 ml

@ -5 ºC

ETHYL METHYL KETONE OXIME
96-29-7

152.5

-29.5

87.12

sol

0.9232

METHYLAMINE
74-89-5

colourless gas or liquid

-6.3

-94

31.1

v sol

0.6628

1.07

290

4.9 ll
20.7 ul

430

2-METHYLAMINO­ETHANOL
109-83-1

viscous liquid

155-156

-4.5

75.11

misc

0.937

2.6

0.7 mm Hg

74 oc

2-DIBUTYLAMINO­ETHANOL
102-81-8

colourless liquid

224-232

173.29

0.859

933

DIISOPROPANOLAMINE
110-97-4

crystals

@ 745 mm Hg

44.5

133.2

sol

0.989

4.6

@ 42 ºC

1.1 ll
5.4 ul

127

374

DIPENTYLAMINE
2050-92-2

colourless to light-yellow liquid

202

-44

157.3

sl sol

0.7771

5.4

52

PROPYLAMINE
107-10-8

colourless liquid

48-49

-83

59.11

sol

0.72

2.0

33.1

2.0 ll
10.4 ul

<-37 oc

317

PROPYLENEDIAMINE
78-90-0

119.5

74.12

v sol

@ 15 ºC

TETRAETHYLENE­PENTAMINE
112-57-2

viscous, hygroscopic liquid; yellow liquid

340

-30

189.3

sol

0.9980

6.53

@ 25 ºC

163 oc

321

TRIALLYLAMINE
102-70-5

liquid

155.5

-70

137.2

0.25 g/100 ml

0.809

4.73

39 oc

TRIBUTYLAMINE
102-82-9

colourless liquid; pale yellow liquid

216.5

-70

185.34

sl sol

0.78

6.39

@ 25 ºC

86 oc

TRIETHANOLAMINE
102-71-6

viscous liquid; colourless to pale yellow

335

20.5

149.2

misc

1.1242

5.1

< 0.01 mm Hg

TRIETHYLAMINE
121-44-8

colourless liquid

89

-115

101.19

sol

0.7275

3.49

@ 31.5 ºC

1.2 ll
8.0 ul

-667 oc

TRIETHYLENETETRAMINE
112-24-3

moderately viscous, yellowish liquid

266.5

12

146.2

v sol

0.9818

5.04

1.3 Pa

1.1 ll
>6.4 ul

118-143 cc

338

TRIISOPROPANOLAMINE
122-20-3

crystals

305

45

191.3

sol

1.0

<0.001

160

320

TRIMETHYLAMINE
75-50-3

colourless gas

3

-117

59.11

v sol

0.6356

2.0

220

2.0 ll
11.6 ul

12 cc

190

TRIPROPYLAMINE
102-69-2

water white liquid

150-156

-94

143.28

0.7558

405

 

Back

Chemical Name

CAS-Number

Physical

Chemical

UN Class or Division /  Subsidiary Risks

ACETALDEHYDE-OXIME
107-29-9

3

ALLYLAMINE
107-11-9

The vapour is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on heating and on burning producing toxic fumes (nitrogen oxides) • Reacts violently with oxidants causing explosion hazard • Reacts violently with acids and acid anhydrides Corrosive to copper (alloys), aluminium, zinc (alloys) and steel

6.1/ 3

BUTYLAMINE
109-73-9

The vapour is heavier than air and may travel along the ground; distant ignition possible

On combustion, forms carbon monoxide and oxides of nitrogen • Reacts with strong oxidants, acids

3/ 8

sec-BUTYLAMINE
13952-84-6

The vapour is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on burning producing toxic fumes and gases (ammonia, oxides of nitrogen) • The substance is a weak base, forming water-soluble salts with acids • Reacts with strong oxidants and strong acids • Corrosive to tin, aluminum, and some steels

CYCLOHEXYLAMINE
108-91-8

The vapour is heavier than air

The substance decomposes on heating producing toxic gases (nitrogen oxides) • The substance is a strong base, it reacts violently with acid and is corrosive • Reacts violently with strong oxidants causing fire hazard

8/ 3

DIALLYLAMINE
124-02-7

The vapour mixes well with air, explosive mixtures are easily formed

May explode on heating • On contact with hot surfaces or flames this substance decomposes forming toxic and corrosive fumes (nitrogen oxides) • The substance is a medium strong base • Reacts violently with oxidants and acids • Attacks copper, tin, aluminium and zinc • Solutions of diallylamine in water may attack glass

6.1/ 3

DIBUTYLAMINE
111-92-2

8/ 3

DICYCLOHEXYLAMINE
101-83-7

8

DIETHANOLAMINE
111-42-2

The vapour is heavier than air

The substance decomposes on burning producing toxic fumes • The solution in water is a medium strong base • Reacts violently with oxidants • Reacts violently with strong acids and anhydrides • Attacks copper

DIETHYLAMINE
109-89-7

The vapour is heavier than air and may travel along the ground; distant ignition possible

On combustion, forms carbon monoxide and oxides of nitrogen • Upon heating, toxic fumes are formed • The solution in water is a medium strong base • Reacts with oxidants causing fire and explosion hazard

3/ 8

2-DIETHYLAMINOETHANOL
100-37-8

On combustion, forms toxic gases (nitrogen oxides) • Reacts violently with oxidants, acids, acid chlorides, and isocyanates • Attacks light metals and copper

3

DIETHYLENETRIAMINE
111-40-0

The vapour is heavier than air

The substance decomposes on burning producing toxic fumes • The solution in water is a strong base, it reacts violently with acid and is corrosive • Reacts violently with strong oxidants, nitric acid, and organic nitro compounds • Attacks many metals in presence of water

8

DIISOPROPYLAMINE
108-18-9

The vapour is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on heating and on burning producing toxic and corrosive fumes (eg • NOx) • The substance is a medium strong base and reacts violently with strong acids • Reacts violently with strong oxidants • Reacts with a lot of compounds like organic chlorides, nitriles, oxides, etc • Attacks many metals forming combustible gas (Hydrogen): aluminium, zinc, copper and tin

3/ 8

DIMETHYLAMINE
124-40-3

The gas is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on burning producing toxic fumes (nitrogen oxides) • The substance is a medium strong base • Reacts violently with strong oxidants, such as chlorine • Reacts violently with mercury causing fire and explosion hazard • Attacks plastics, rubber, and coatings

2.1

DIMETHYLETHANOLAMINE
108-01-0

The vapour is heavier than air

Reacts with strong oxidants and many other substances, causing fire and explosion hazard • Attacks copper

8/ 3

3,3'-DIAMINODIPROPYLAMINE
56-18-8

6.1

DIISOPROPANOLAMINE
110-97-4

Dust explosion possible if in powder or granular form, mixed with air

The substance decomposes on heating andon burning producing toxic gases (nitrogen oxides) • The substance is a strong oxidant and reacts with combustible and reducing materials • The solution in water is a medium strong base and reacts with strong acids • Reacts violently with strong oxidants causing fire and explosion hazard

ETHANOLAMINE
141-43-5

8

ETHYLAMINE
75-04-7

The gas is heavier than air and may travel along the ground; distant ignition possible • Do not use compressed air when filling, emptying, or processing

The substance decomposes on heating producing toxic gases including nitrogen oxides • The solution in water is a strong base • It reacts violently with acid, strong oxidants and organic compounds causing fire and explosion hazard • Attacks many non-ferrous metals and plastics

3/ 8

ETHYLENEDIAMINE
107-15-3

The substance decomposes on heating producing toxic fumes (nitrogen oxides) • The substance is a medium strong base • Reacts violently with chlorinated organic compounds strong oxidants

8/ 3

ETHYLENIMINE
151-56-4

The vapour is heavier than air Compilerand may travel along the ground; distant ignition possible • The vapour mixes well with air, explosive mixtures are easily formed

The substance may polymerize under the influence of aqueous acidic conditions, acids, oxidising materials • On combustion, forms toxic and irritating fumes including nitrogen oxides • The substance is a medium strong base

6.1/ 3

HEXAMETHYLENEDIAMINE
124-09-4

Upon heating, toxic fumes are formed • The solution in water is a strong base, it reacts violently with acid and is corrosive • Reacts with oxidants • Attacks many metals in presence of water

8

ISOBUTYLAMINE
78-81-9

3/ 8

ISOPHORONE DIAMINE
2855-13-2

May explode on heating • Reacts with brass, copper, zinc and tin • Reacts violently with acids • Attacks many metals

8

ISOPROPANOLAMINE
78-96-6

On combustion, forms nitrous oxide • Reacts with strong oxidants

ISOPROPYLAMINE
75-31-0

3

METHYLAMINE
74-89-5

The gas is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on burning producing toxic fumes (nitrogen oxides) • The substance is a medium strong base • Reacts violently with mercury causing fire and explosion hazard • Reacts violently with strong oxidants, such as chlorine

2.1

DIPENTYLAMINE
2050-92-2

The substance decomposes on heating producing toxic and irritating gases (nitrogen oxides) • Reacts with oxidants

PROPYLAMINE
107-10-8

The vapour is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on heating or on burning producing toxic gases (nitrogen oxides) • The substance is a medium strong base • Reacts violently with oxidants and mercury causing fire and explosion hazard, Reacts violently with concentrated acids, nitroparrafins, halogenated hydrocarbons, alcohols and many other compounds • Attacks many metals and alloys, especially copper • Is corrosive to copper (alloys), aluminium, zinc (alloys) and galvanised surfaces • Solutions of propylamine in water may attack glass

3/ 8

TETRAETHYLENEPENTAMINE
112-57-2

8

TRIALLYLAMINE
102-70-5

3/ 8

TRIBUTYLAMINE
102-82-9

8

TRIETHYLAMINE
121-44-8

3/ 8

TRIETHYLENETETRAMINE
112-24-3

On combustion, forms toxic fumes of carbon monoxide and nitrogen oxides • The substance is a medium strong base • Reacts violently with oxidants causing fire and explosion hazard • Reacts with acid chlorides, acid anhydrides, aldehydes, ketones, halogenated organic compounds and acrylates • Attacks metals such as aluminium, zinc, copper and its alloys

TRIISOPROPANOLAMINE
122-20-3

On combustion, forms toxic gases of carbon and nitrogen oxides • Reacts with strong oxidants and acids

TRIMETHYLAMINE
75-50-3

The gas is heavier than air and may travel along the ground; distant ignition possible

The substance decomposes on burning producing toxic gases (nitrous oxides) • The substance is a medium strong base • Reacts violently with mercury causing fire and explosion hazard • Reacts violently with strong oxidants, such as chlorine

2.1

TRIPROPYLAMINE
102-69-2

3/ 8

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

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Saturday, 06 August 2011 03:18

Amines, Aliphatic: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

ALLYLAMINE      107-11-9

eyes; skin; resp tract; lungs; heart

skin

Inhalation: burning sensation, cough, chest pain, shortness of breath, sore throat

Skin: may be absorbed, redness, pain, blisters

Eyes: severe eye irritation, redness, pain, tear drawing, blurred vision, loss of vision

Ingestion: burning sensation, headache, nausea, weakness

1-AMINO-2-PROPANOL    78-96-6

eyes; skin; resp tract; lungs

Inhalation: burning sensation, cough, headache, laboured breathing, nausea, sore throat

BUTYLAMINE     109-73-9

eyes; skin; resp tract; lungs; CNS

skin

Inhalation: burning sensation, cough, dizziness, unconsciousness

Skin: may be absorbed, redness, roughness, skin burns, burning sensation, blisters

Eyes: pain, burns, loss of vision

Ingestion: cough, dizziness, nausea, unconsciousness, vomiting

Resp sys; eyes; skinInh, abs, ing, con

Irrit eyes, skin, nose, throat; head; skin flush, burns

sec-BUTYLAMINE     13952-84-6

eyes; skin; resp tract; lungs

skin

Inhalation: cough, laboured breathing, sore throat, symptoms may be delayed

Skin: redness, skin burns, pain

Eyes: redness, pain, blurred vision, severe deep burns

Ingestion: diarrhoea, sore throat, vomiting

CYCLOHEXYLAMINE     108-91-8

eyes; skin; resp tract; lungs; CNS

skin

Eyes; skin; resp sys; CNSInh, abs, ing, con

Irrit eyes, skin, muc memb, resp sys; eye, skin burns; skin sens; cough, pulm edema; drow, li-head, dizz; diarr, nau, vomit

DIALLYLAMINE   124-02-7

eyes; skin ; resp tract; lungs; heart

burning sensation, cough, sore throat, chest pain, shortness of breath

DIETHYLAMINE  109-89-7

eyes; skin; resp tract; lungs

skin

Inhalation: burning sensation, cough, chest pain

Skin: roughness, skin burns, pain

Eyes: pain, blurred vision, severe deep burns

Ingestion: abdominal cramps, abdominal pain, burning sensation, cough, sore throat

Eyes; skin; resp sys; CNSInh, abs, ing, con

Irrit eyes, skin, resp sys; in animals: myocardial degeneration

2-DIETHYLAMINOETHANOL     100-37-8

Inhalation: cough, laboured breathing, nausea, shortness of breath, sore throat, vomiting

Resp sys; skin; eyesInh, abs, ing, con

Irrit eyes, skin, resp sys; nau, vomit

DIETHYLENETRIAMINE     111-40-0

eyes; skin; resp tract; lungs

skin; resp tract

Inhalation: burning sensation, cough, headache, laboured breathing, nausea, sore throat, symptoms may be delayed

Skin: severe skin burns, pain

Eyes: pain, loss of vision, severe deep burns

Ingestion: abdominal pain, sore throat

Eyes; skin; resp sysInh, abs, ing, con

Irrit eyes, skin, muc memb, upper resp sys; derm, skin sens; eye, skin nec; cough, dysp, pulm sens

DIETHANOLAMINE     111-42-2

eyes; skin; resp tract

skin; resp tract

Inhalation: burning sensation, headache, nausea, sore throat, vomiting

Skin: redness, burning sensation

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain, burning sensation

Eyes; skin; resp sysIng, ing, con

irrit eyes, skin, nose, throat; eye burns, corn nec; skin burns; lac, cough, sneez

DIISOPROPANOLAMINE     110-97-4

eyes; skin

skin

Skin: redness, burning sensation

Eyes: redness, pain, blurred vision

DIISOPROPYLAMINE     108-18-9

eyes; resp tract; lungs

skin

Inhalation: cough, laboured breathing, nausea, sore throat

Skin: may be absorbed, dry skin, redness, burning sensation

Eyes: redness, pain, temporary or even permanent loss of vision

Ingestion: corrosive, abdominal cramps, cough, nausea, sore throat

Eyes; skin; resp sysInh, abs, ing, con

Irrit eyes, skin, resp sys; nau, vomit; head; vis dist

DIMETHYLAMINE     124-40-3

eyes; skin; resp tract; lungs

skin

Inhalation: abdominal pain, burning sensation, cough, diarrhoea, laboured breathing, shortness of breath, sore throat

Skin: redness, skin burns, pain

Eyes: redness, pain, blurred vision, severe deep burns

Resp sys; skin; eyesInh, con, (liq)

Irrit nose, throat; sneez, cough, dysp; pulm edema; conj; derm; liq: frostbite

2-DIMETHYLAMINOETHANOL     108-01-0

eyes; skin; resp tract; lungs

skin

Inhalation: cough, laboured breathing, symptoms may be delayed

Skin: may be absorbed, redness, pain

Eyes: pain, severe deep burns

Ingestion: abdominal pain, nausea, vomiting

DIPENTYLAMINE     2050-92-2

eyes; skin; resp tract

cough

1,2-ETHANEDIAMINE     107-15-3

eyes; skin; resp tract; lungs; liver; kideys

skin; resp tract

Inhalation: burning sensation, cough, laboured breathing, shortness of breath, sore throat

Skin: may be absorbed, redness, skin burns, pain

Eyes: redness, pain, blurred vision

Ingestion: abdominal pain, diarrhoea, sore throat, vomiting

Resp sys; liver; kidneys; skinInh, abs, ing, con

Irrit nose, resp sys; sens derm; asthma; liver, kidney damage

ETHANOLAMINE 141-43-5

Resp sys; skin; eyes; CNSInh, ing, con

Irrit eyes, skin, resp sys; leth

ETHYLAMINE     75-04-7

eyes; skin; resp tract

kidneys; lungs

Inhalation: cough, laboured breathing, sore throat

Skin: may be absorbed, redness, burning sensation

Eyes: redness, pain

Ingestion: abdominal pain, burning sensation

Resp sys; eyes; skinInh, abs (liq), ing (liq), con (liq)

Irrit eyes, skin, resp sys; skin burns; derm

ETHYLENIMINE  151-56-4

eyes; skin; resp tract; lungs; CNS; kidneys; liver

skin

Inhalation: cough, dizziness, headache, laboured breathing, nausea, vomiting, symptoms may be delayed

Skin: may be absorbed, redness, skin burns, blisters

Eyes: redness, pain, severe deep burns

Ingestion: Vomiting

Eyes; lungs; skin; liver; kidneys; resp sys; In animals: lung & liver tumorsIng, abs, ing, con

Irrit eyes, skin, nose, throat; nau, vomit; head, dizz; pulm edema; liver, kidney damage; eye burns; skin sens; (carc)

HEXAMETHYLENEDIAMINE     124-09-4

eyes; skin; resp tract

skin

Inhalation: cough, laboured breathing, shortness of breath

Skin: redness, pain

Eyes: redness, pain

Ingestion: abdominal cramps, abdominal pain

ISOBUTANOLAMINE     124-68-5

eyes; skin; resp tract; lungs

ISOPHORONE DIAMINE     2855-13-2

eyes; skin; resp tract; lungs

skin; lungs

Inhalation: burning sensation, cough, headache, cardiac dysrhythmia, symptoms may be delayed

Skin: may be absorbed, redness, skin burns, burning sensation, pain

Eyes: redness, pain, blurred vision, loss of vision, severe deep burns

Ingestion: abdominal pain, burning sensation, sore throat

ISOPROPYLAMINE         75-31-0

Resp sys; skin; eyesInh, abs, ing, con

Irrit eyes, skin, nose, throat; pulm edema; vis dist; eye, skin burns; derm

METHYLAMINE   74-89-5

eyes; skin; resp tract; lungs

skin

Inhalation: abdominal cramps, cough, diarrhoea, laboured breathing, shortness of breath, sore throat, vomiting

Skin: redness, pain

Eyes: redness, pain

Ingestion: abdominal cramps

Resp sys; eyes; skinInh, abs (soln), ing (soln), con (liqsoln)

irrit eyes, skin, resp sys; cough; skin, muc memb burns; derm; conj; liq: frostbite

PROPYLAMINE   107-10-8

eyes; skin; resp tract; lungs

Inhalation: burning sensation, cough, sore throat, shortness of breath

TRIETHYLAMINE 121-44-8

Resp sys; eyes; skin; CVS; liver; kidneysIng, abs, ing, con

Irrit eyes, skin, resp sys; in animals: myocardial, kidney, liver damage

TRIETHYLENETETRAMINE     112-24-3

eyes; skin; resp tract; lungs

skin

Inhalation: burning sensation, cough, laboured breathing

Skin: redness, pain, blisters

Eyes: redness, pain, severe deep burns

Ingestion: abdominal pain, burning sensation, weakness

TRIISOPROPANOLAMINE     122-20-3

eyes; skin; resp tract; lungs

Inhalation: burning sensation, cough, laboured breathing, sore throat

TRIMETHYLAMINE          75-50-3

Inhalation: abdominal pain, burning sensation, cough, diarrhoea, laboured breathing, shortness of breath, sore throat

Skin: redness, skin burns, pain

Eyes: redness, pain, blurred vision, severe deep burns

Eyes; skin; resp sysInh, ing (soln), con

Irrit eyes, skin, nose, throat, resp sys; cough, dysp, delayed pulm edema; blurred vision, corn nec; skin burns; liq: frostbite

 

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Saturday, 06 August 2011 03:16

Amines, Aliphatic: Chemical Identification

Chemical Formula

Chemical

Synonyms
UN Code

CAS-Number

107299

ACETALDEHYDE-OXIME

Acetaldoxime;
Aldoxime;
Ethanal oxime;
Ethylidenehydroxylamine
UN2332

107-29-9

107119

ALLYLAMINE

Allylamine;
3-Aminopropene;
3-Aminopropylene;
Monoallylamine;
2-Propenamine
UN2334

107-11-9

140954

1,3-BIS(HYDROXYMETHYL)UREA

N,N'-Bis(hydroxymethyl)urea;
N,N'-Dihydroxymethylurea;
Dimethanol urea;
Dimethylolurea;
N,N'-Dimethylolurea;
1,3-Dimethylolurea;
Oxymethurea

140-95-4

590885

1,3-BUTANEDIAMINE

1,3-Diaminobutane

590-88-5

109739

BUTYLAMINE

1-Aminobutane;
1-Butanamine;
Monobutylamine
UN1125

109-73-9

13952846

sec-BUTYLAMINE

2-Aminobutane;
2-Butanamine;
1-Methylpropylamine,

13952-84-6

75649

tert-BUTYLAMINE

2-Aminoisobutane;
2-Amino-2-methylpropane;
1,1-Dimethylethylamine;
Trimethylaminomethane

75-64-9

108918

CYCLOHEXYLAMINE

Aminocyclohexane;
Aminohexahydrobenzene;
Cyclohexanamine;
Hexahydroaniline
UN2357

108-91-8

124027

DIALLYLAMINE

Di-2-propenylamine ;
N-2-Propenyl 2-propen-1-amine
UN2359

124-02-7

56188

3,3'-DIAMINODIPROPYLAMINE

Aminobis(propylamine);
Dipropylenetriamine;
Iminobis(propylamine);
3,3'-Iminobis(propylamine)
UN2269

56-18-8

111922

DIBUTYLAMINE

Butyl-1-butanamine;
N-Dibutylamine
UN2248

111-92-2

102818

2-DIBUTYLAMINOETHANOL

Dibutylaminoethanol;
N,N-Dibutylethanolamine;
N,N-Dibutyl-N-(2-hydroxyethyl)amine
UN2873

102-81-8

51752

2,2'-DICHLORO-N-METHYLDIETHYL­AMINE

Bis(2-chloroethyl)methylamine;
2-Chloro-n-(2-chloroethyl)-N-methyl­ethanamine;
N,N-Di(chloroethyl)methylamine;
Methylbis(2-chloroethyl)amine

51-75-2

101837

DICYCLOHEXYLAMINE

N-Cyclohexylcyclohexanamine;
N,N-Diclohexylamine;
Dodecahydrodiphenylamine
UN2565

101-83-7

109897

DIETHYLAMINE

Diethamine;
N,N-Diethylamine;
N-Ethyl ethanamine
UN1154

109-89-7

100378

2-DIETHYLAMINOETHANOL

Diethylaminoethanol;
Diethylethanolamine;
N,N-Diethylethanolamine
UN2686

100-37-8

111400

DIETHYLENETRIAMINE

Aminoethylethandiamine;
Bis(2-aminoethyl)amine;
2,2'-Diaminodiethylamine;
Ethylamine, 2,2'-Iminobis-;
Ethylenediamine-N-(2-aminoethyl)-
UN2079

111-40-0

111422

DIETHANOLAMINE

Bis(2-hydroxyethyl)amine;
Diethanolamine;
Diethylolamine;
2,2'-Dihydroxydiethylamine ;
Di(2-hydroxyethyl)amine

111-42-2

110974

DIISOPROPANOLAMINE

Bis(2-propanol)amine;
Bis(2-hydroxypropyl)amine;
DIPA;
1,1'-Iminobis-2-propanol;
1,1’-Iminodi-2-propanol

110-97-4

108189

DIISOPROPYLAMINE

N-(1-Methylethyl)-2-propanamine
UN1158

108-18-9

109557

3-DIMETHYLAMINOPROPYLAMINE

1-Amino-3-dimethylaminopropane;
N,N-Dimethyl-1,3-propanediamine;
N,N-Dimethyl-n-(3-aminopropyl)amine;
3-(Dimethylamino)propylamine;
N,N-Dimethyl-1,3-propylenediamine

109-55-7

124403

DIMETHYLAMINE

DMA;
Methanamine, N-Methylmethanamine
UN1032
UN1160

124-40-3

506592

DIMETHYLAMINE HYDROCHLORIDE

Dimethylammonium chloride;
Hydrochloric acid dimethylamine;
N-Methylmethanamine hydrochloride

506-59-2

108010

2-DIMETHYLAMINOETHANOL

Dimethylaminoethanol;
Dimethylethanolamine;
N,N-Dimethyl-N-(2-hydroxyethyl)amine;
DMAE
UN2051

108-01-0

3033623

BIS(2-DIMETHYLAMINOETHYL)ETHER

Ethylamine, 2,2'-oxybis(N,N-Dimethyl;
NIAX Catalyst A1

3033-62-3

2050922

DIPENTYLAMINE

Diamyl amine;
Di-N-amylamine;
1-Pentanamine, N-Pentyl
UN2841

2050-92-2

141435

ETHANOLAMINE

2-Aminoethanol;
Ethanolamine;
Glycinol;
2-Hydroxyethylamine;
Monoethanolamine
UN2491

141-43-5

75047

ETHYLAMINE

Aminoethane;
1-Aminoethane;
Ethanamine;
Monoethylamine
UN1036
UN2270

75-04-7

107153

ETHYLENEDIAMINE

1,2-Diaminoethane;
Dimethylenediamine;
1,2-Ethanediamine;
Ethylendiamine;
Ethylenediamine;
1,2-Ethylenediamine
UN1604

107-15-3

151564

ETHYLENIMINE

Dihydroazirene;
Dihydro-1H-azirine;
Dimethyleneimine;
Dimethylenimine
UN1185

151-56-4

104756

2-ETHYLHEXYLAMINE

2-Ethyl hexylamine
UN2276

104-75-6

96297

ETHYLMETHYLKETONE OXIME

2-Butanone, oxime;
Ethyl methyl ketoxime;
MEK-oxime;
Methyl ethyl ketoxime

96-29-7

124094

HEXAMETHYLENEDIAMINE

1,6-Diaminohexane;
Hexamethylenediamine;
1,6-Hexamethylenediamine
UN1783
UN2280

124-09-4

100970

HEXAMETHYLENETETRAMINE

Formamine;
Hexaform;
1,6-Hexanediamine;
Hexamine;
Methamin;
Methenamine
UN1328

100-97-0

111411

HYDROXYETHYLETHYLENEDIAMINE

N-Aminoethylethanolamine;
Ethanolethylene diamine;
N-Hydroxyethyl-1,2-ethanediamine Monoethanolethylenediamine;
2-((2-Aminoethyl)amino)ethanol

111-41-1

124685

ISOBUTANOLAMINE

2-Aminodimethylethanol;
2-Amino-2-methylpropanol;
2-Amino-2-propanol;
Isobutanol-2-amine

124-68-5

78819

ISOBUTYLAMINE

1-Amino-2-methylpropane;
Monoisobutylamine;
1-Propanamine, 2-methyl-
UN1214

78-81-9

78966

ISOPROPANOLAMINE

a-Aminoisopropyl alcohol;
2-Hydroxypropylamine;
Isopropanolamine;
1-Methyl-2-aminoethanol;
Mono-iso-propanolamine

78-96-6

75310

ISOPROPYLAMINE

1-Methylethylamine;
Monoisopropylamine;
2-Propanamine;
sec-Propylamine;
2-Propylamine
UN1221

75-31-0

74895

METHYLAMINE

Aminomethane;
Carbinamine;
Mercurialin;
Monomethylamine
UN1061
UN1235

74-89-5

109831

2-METHYLAMINOETHANOL

N-Methylaminoethanol;
Methylethanolamine;
Monomethylaminoethanol

109-83-1

462942

1,5-PENTANEDIAMINE

Cadaverin;
1,5-Diaminopentane;
Pentamethylenediamine;
1,5-Pentamethylenediamine

462-94-2

109762

1,3-PROPANEDIAMINE

1,3-Diaminopropane;
1,3-Propylenediamine;
Trimethylenediamine

109-76-2

107108

PROPYLAMINE

1-Aminopropane;
Monopropylamine;
Propanamine;
1-Propylamine
UN1277

107-10-8

78900

PROPYLENEDIAMINE1,2-PROPANE­DIAMINE

1,2-Diaminopropane;
1,2-Propanediamine;
1,2-Propylenediamine;
Propylenediamine
UN2258

78-90-0

112572

TETRAETHYLENEPENTAMINE

D.E.H. 26;
1,4,7,10,13-Pentaazatridecane;
1,2-Ethanediamine, N-(2-amino­ethyl)-N'-(2-((2-aminoethyl)amino)ethyl
UN2320

112-57-2

102705

TRIALLYLAMINE

N,N-Di-2-propenyl-2-propen-1-amine;
2-Propen-1-amine, N,N-Di-2-propenyl-
UN2610

102-70-5

102829

TRIBUTYLAMINE

Tributylamine;
Tri-N-butylamine;
Tris-N-butylamine
UN2542

102-82-9

121448

TRIETHYLAMINE

Diethylaminoethane;
N,N-Diethylethanamine;
Ethanamine, N,N-Diethyl
UN1296

121-44-8

112243

TRIETHYLENETETRAMINE

N,N-Bis(2-aminoethyl)-1,2-Diamino­ethane;
N,N'-Bis(2-aminoethyl)ethylenediamine;
1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-;
Ethylenediamine, N,N'-Bis(2-aminoethyl)-
UN2259

112-24-3

102716

TRIETHANOLAMINE

Nitrilo-2,2',2''-triethanol;
Triethanolamine;
Tri(hydroxyethyl)amine;
Trihydroxytriethylamine

102-71-6

122203

TRIISOPROPANOLAMINE

Triisopropanolamine;
Tris(2-hydroxypropyl)amine;
Tris(2-hydroxy-1-propyl)amine

122-20-3

75503

TRIMETHYLAMINE

Methanamine, N,N-dimethyl-;
TMA
UN1083
UN1297

75-50-3

102692

TRIPROPYLAMINE

N,N-Dipropyl-1-propanamine
UN2260

102-69-2

 

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Saturday, 06 August 2011 03:11

Amides: Physical & Chemical Properties

Chemical Name

CAS-Number

Colour/Form

Boiling Point (°C)

Melting Point (°C)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (°C)

Auto Ignition Point (°C)

ACETAMIDE
60-35-5

deliquescent hexagonal crystals; trigonal monoclinic crystals

222

81

59.07

1 g/0.5 ml

1.159

<0.1

2-ACETYLAMINO­FLUORENE
53-96-3

tan, crystalline solid

194

223.26

insol

ACRYLAMIDE
79-06-1

flake-like crystals from benzene;white crystalline solid; leaf crystals from benzene

125

84.5

71.08

v sol

1.122

2.45

1 Pa

138 cc

424

BENZOTHIAZYL-2-
CYCLOHEXYLSULFENAMIDE
95-33-0

cream-coloured powder

93-100

264.41

insol

1.27

2-CHLOROACETAMIDE
79-07-2

crystals

225

120

93.5

sol

3.2

0.007

COLCHICINE
64-86-8

156

399.42

v sol

CYCLOHEXIMIDE
66-81-9

plates from amyl acetate, water or 30% methanol; colourless crystals

119.5-121

281.34

CYCLOPHOSPHAMIDE
50-18-0

fine, white, crystalline powder; liquifies on loss of its water of crystallization

49.5-53

261.10

1/25 parts

112

4,4'-DIACETYLBENZIDINE
613-35-4

328.3

268.30

DIETHYLCARBAMOYL CHLORIDE
88-10-8

liquid

187

-44

135.6

sol

4.1

DIMETHYL ACETAMIDE
127-19-5

colourless oily liquid

165

-20

87.12

misc

@ 25 °C/4 °C

3.01

0.33

1.8 ll
11.5 ul

70 oc

490

DIMETHYL CARBAMOYL CHLORIDE
79-44-7

liquid

167

-33

107.5

1.1678

3.73

DIMETHYLFORMAMIDE
68-12-2

colourless to very slightly yellow liquid; water-white liquid

153

-60.4

73.09

misc

@ 25 °C/4 °C

2.51

0.36

2.2 ll
15.2 ul

67 oc

354

N,N'-ETHYLENE BIS(STEARAMIDE)
110-30-5

solid

135-146

593.04

insol

0.97

280 oc

FORMAMIDE
75-12-7

slightly viscous, colourless oily liquid

210.5 decomp

2.55

45.04

misc

1.1334

1.6

2 Pa

154 oc

>500

METHYLFORMAMIDE
123-39-7

180-185

-3.8

59.07

v sol

@ 19 °C

@ 25 °C

SODIUM AMIDE
7782-92-5

white crystalline powder

400

210

39.02

sol

1.39

 

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Saturday, 06 August 2011 03:09

Amides: Physical & Chemical Hazards

Chemical Name

CAS-Number

Physical

Chemical

UN Class or Division /  Subsidiary Risks

ACETAMIDE
60-35-5

The substance decomposes on heating, producing toxic fumes • The solution in water is a strong base, it reacts violently with acid and is corrosive • Reacts with oxidants, reducing agents, bases, and acids

ACRYLAMIDE
79-06-1

The substance may polymerize violently due to heating or under the influence of light • The substance decomposes on heating producing toxic gases (nitrous oxides) • Reacts violently with oxidants

6.1

2-CHLOROACETAMIDE
79-07-2

The substance decomposes on heating producing toxic fumes including nitrogen oxides and chlorine • Reacts with strong oxidants, strong reducing agents, strong acids and strong bases

CYCLOPHOSPHAMIDE
50-18-0

The substance decomposes on heating, on contact with moisture, light, producing toxic fumes • Reacts with strong oxidants, strong acids, strong bases

DIMETHYL ACETAMIDE
127-19-5

The substance decomposes on heating producing toxic fumes (nitrogen oxides) • Attacks many plastics

DIMETHYL CARBAMOYL CHLORIDE
79-44-7

8

DIMETHYLFORMAMIDE
68-12-2

On combustion, forms toxic gases (carbon monoxide, dimethylamine and oxides of nitrogen) • Reacts with oxidants

3

N,N'-ETHYLENE BIS(STEARAMIDE)
110-30-5

Dust explosion possible if in powder or granular form, mixed with air

On combustion, forms toxic gases • The substance decomposes on heating and on burning producing toxic fumes (nitrogen oxides) • Reacts with strong oxidants

FORMAMIDE
75-12-7

On combustion, forms toxic gases (nitrogen oxides) • The substance decomposes on heating at 200 °C or above producing ammonia, water, carbon monoxide and hydrogen cyanide • Reacts vigorously with oxidizing materials • Attacks copper and natural rubber • Incompatible with iodine, pyridine and sulfur trioxide

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

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Saturday, 06 August 2011 03:08

Amides: Health Hazards

Chemical Name

CAS-Number

ICSC Short-Term Exposure

ICSC Long-Term Exposure

ICSC Routes of Exposure and Symptoms

US NIOSH Target Organs & Routes of Entry

US NIOSH Symptoms

ACETAMIDE       60-35-5

eyes; skin; resp tract

Inhalation: cough, shortness of breath

Skin: redness, pain

Eyes: pain, redness, blurred vision

Ingestion: sore throat, burning sensation

2-ACETYLAMINOFLUORENE     53-96-3

Liver; bladder; kidneys; pancreas; skin; lungs (in animals: tumors of the liver; bladder, pancreas, skin & lungs) Inh, abs, ing, con

Reduced function of liver, kidneys, bladder, pancreas (carc)

ACRYLAMIDE     79-06-1

skin; resp tract; CNS; liver

PNS; CNS

Inhalation: cough, sore throat, weakness

Skin: may be absorbed, redness, pain

Eyes: redness, pain

Ingestion: abdominal pain, weakness

CNS; PNS; skin; eyes, repro sys (in animals: tumors of the lungs, testes, thyroid & adrenal glands) Inh, abs, ing, con

Irrit eyes, skin; ataxia, numb limbs, pares; musc weak; absent deep tendon reflex; hand sweat; ftg, leth; repro effects (carc)

2-CHLOROACETAMIDE    79-07-2

eyes; skin; resp tract; heart; liver; spleen

skin

Inhalation: burning sensation, cough, sore throat

Skin: redness, pain

Eyes: redness, pain

Ingestion: sore throat

CYCLOPHOSPHAMIDE    50-18-0

eyes; skin; resp tract; kidneys; bladder; CVS; CNS; GI tract; liver; heart; blood

skin

Inhalation: diarrhoea, dizziness, loss of hair, darkening of skin and finger nails, nausea, vomiting

Skin: may be absorbed

DIMETHYL ACETAMIDE     127-19-5

eyes; skin; resp tract

skin; liver; kidneys

Inhalation: headache, nausea, vomiting

Skin: may be absorbed, redness

Eyes: Vapour will be absorbed, redness, pain

CNS; liver; skin Inh, abs, ing, con

irrit skin; jaun, liver damage; depres, leth, halu, delusions

DIMETHYLFORMAMIDE    68-12-2

eyes; skin; resp tract; liver; CNS

liver

Inhalation: loss of appetite, abdominal pain, diarrhoea, dizziness, nausea, vomiting, nervous agitation, facial flushing and alcohol intolerance

Skin: may be absorbed, dry skin, redness, roughness

Eyes: redness, pain

Eyes; liver; kidneys; CVS; skin; resp sys Inh, abs, ing, con

Irrit eyes, skin, resp sys; nau, vomit, colic; liver damage, enlarged liver; high BP; face flush; derm; in animals: kidney, heart damage

FORMAMIDE      75-12-7

lungs; CNS

liver

Inhalation: drowsiness, headache, nausea, unconsciousness

Skin: may be absorbed, redness

Eyes: redness

Ingestion: abdominal pain

Eyes; skin; resp sys; CNS; repro sys Inh, ing, con

Irrit eyes, skin, muc memb; drow, ftg; nau, acidosis; skin eruptions; in animals: repro effects

 

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Saturday, 06 August 2011 03:04

Amides: Chemical Identification

Chemical Formula

Chemical

Synonyms
UN Code

CAS-number

60355

ACETAMIDE

Acetic acid amide;
Acetimidic acid;
Ethanamide;
Methanecarboxamide

60-35-5

53963

2-ACETYLAMINOFLUORENE

2-Acetaminofluorene;
Acetoaminofluorene;
N-Acetyl-2-aminofluorene;
2-(Acetylamino)fluorene;
2-Fluorenylacetamide

53-96-3

79061

ACRYLAMIDE

Acrylic amide;
Ethylenecarboxamide;
Propenamide;
2-Propenamide;
Vinyl amide
UN2074

79-06-1

95330

BENZOTHIAZYL-2-CYCLOHEXYL­SULFENAMIDE

N-Cyclohexyl-2-benzothiazolesulfen­amide;
N-Cyclohexyl-2-benzothiazylsulfenamide

95-33-0

79072

2-CHLOROACETAMIDE

Chloroacetamide;
a-Chloroacetamide;
2-Chloroethanamide

79-07-2

2832191

2-CHLORO-N-HYDROXYMETHYL­ACETAMIDE

Chloracetamide-N-metholol

2832-19-1

64868

COLCHICINE

Acetamide, N-(5,6,7,9-Tetrahydro-1,2,3,10-tetramethoxy-9-oxobenzo-a-(heptalen-­7-yl)-;
N-Acetyl trimethylcolchicinic acid methylether;
Benzo(a)heptalen-9(5h)-one, 7-acetamido-6,7-dihydro-1,2,3,10-tetra­methoxy-

64-86-8

66819

CYCLOHEXIMIDE

b-(2-(3,5-Dimethyl-2-oxocyclohexyl)-2-­hydroxyethyl)glutarimide;
3-(2-(3,5-Dimethyl-2-oxocyclohexyl)-2-hydroxyethyl)­glutarimide

66-81-9

50180

CYCLOPHOSPHAMIDE

Cyclophosphane;
N,n-bis(2-chloroethyl)-N',o-propylenephosphoric acid ester diamide;
N,N-Bis(2-chloroethyl)tetra­hydro-2h-1,3,2-oxazaphosphorin-2-amine 2-oxide;
Bis(2-chloroethyl)phosphoramide-cyclic propanolamide ester

50-18-0

613354

4,4'-DIACETYLBENZIDINE

4,4'-Diacetamidobiphenyl;
4,4'-Diacetylaminobiphenyl;
Diacetylbenzidine;
N,N'-Diacetyl benzidine

613-35-4

88108

DIETHYLCARBAMOYL CHLORIDE

Diethylcarbamic chloride;
N,N-Diethylcarbamoyl chloride;
Diethylcarbamyl chloride;
Diethylchloroformamide;
N,N-Diethylchloroformamide

88-10-8

127195

DIMETHYL ACETAMIDE

Acetdimethylamide;
Acetic acid, dimethylamide;
N,N-Dimethylacetamide;
Dimethylacetone amide;
Dimethylamide acetate

127-19-5

79447

DIMETHYL CARBAMOYL CHLORIDE

Chloroformic acid dimethylamide;
(Dimethylamino)carbonyl chloride;
Dimethylcarbamic acid chloride;
Dimethylcarbamic chloride;
Dimethylchloroformamide
UN2262

79-44-7

68122

DIMETHYLFORMAMIDE

N,N-Dimethyl formamide;
N,N-Dimethylmethanamide;
N-Formyldimethylamine
UN2265

68-12-2

110305

N,N'-ETHYLENE BIS(STEARAMIDE)

1,2-Bis(octadecanamido)ethane;
N,N'-Ethylene distearylamide;
N,N'-Ethylene bis(octadecanamine)

110-30-5

75127

FORMAMIDE

Carbamaldehyde;
Methanamide

75-12-7

123397

METHYLFORMAMIDE

N-Methylformamide;
Monomethylformamide

123-39-7

7782925

SODIUM AMIDE

7782-92-5

 

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Page 16 of 122

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Contents

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