Sunday, 07 August 2011 06:55

Hydrocarbons, Saturated & Alicyclic: Physical & Chemical Hazards

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Chemical Name
CAS-Number

Physical

Chemical

UN Class or Division /  Subsidiary Risks

BUTANE
106-97-8

The gas is heavier than air and may travel along the ground; distant ignition possible, and may accumulate in low ceiling spaces causing deficiency of oxygen

On combustion, forms toxic gases; COx

2.1

CYCLOHEXANE
110-82-7

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

3

CYCLOPENTANE
287-92-3

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

3

CYCLOPROPANE
75-19-4

2.1

DECANE
124-18-5

Can react with oxidizing materials

3

2,3-DIMETHYLBUTANE
79-29-8

3

ETHANE
74-84-0

The gas mixes well with air, explosive mixtures are easily formed

On combustion, forms toxic gases

2.1

HEPTANE
142-82-5

The vapour is heavier than air and may travel along the ground; distant ignition possible • If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc

Reacts violently with strong oxidants • Attacks many plastics

3

HEXANE
110-54-3

The vapour is heavier than air and may travel along the ground; distant ignition possible

Reacts with strong oxidants causing fire and explosion hazard

3

ISOBUTANE
75-28-5

2.1

2-METHYLBUTANE
78-78-4

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

May explode on heating • On combustion, forms acrid smoke and irritating fumes • Reacts violently with oxidants

3

METHYLCYCLOHEXANE
108-87-2

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

Reacts violently with strong oxidants causing fire and explosion hazard

3

2-METHYLHEPTANE
592-27-8

The vapour is heavier than air and may travel along the ground; distant ignition possible

Upon heating, toxic fumes are formed • Reacts with oxidants

3-METHYLPENTANE
96-14-0

3

NONANE
111-84-2

3

OCTANE
111-65-9

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

Reacts with strong oxidants causing fire and explosion hazard • Attacks some forms of plastics, rubber and coatings

3

PENTANE
109-66-0

The vapour is heavier than air and may travel along the ground; distant ignition possible

On combustion, forms toxic gases of carbon oxides • Reacts with strong oxidants (eg, peroxides, nitrates and perchlorates), causing fire and explosion hazard • Attacks some forms of plastics, rubber and coatings

3

PROPANE
74-98-6

The gas is heavier than air, and may travel along the ground; distant ignition possible • May accumulate in low ceiling spaces causing deficiency of oxygen

On combustion, forms toxic fumes

2.1

2,2,4-TRIMETHYLPENTANE
540-84-1

The vapour is heavier than air and may travel along the ground; distant ignition possible • As a result of flow, agitation, etc, electrostatic charges can be generated

Heating may cause violent combustion or explosion • Reacts with strong oxidants

3

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

 

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