Guide to Chemicals

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
86884	ANTU	a-Naphthyl thiourea; 1-Naphthalenylthiourea; 1-Naphthyl thiourea; N-(1-Naphthyl)-2-thiourea; 1-(1-Naphthyl)-2-thiourea UN1651	86-88-4
98099	BENZENESULPHONYL CHLORIDE	Benzenesulphonic chloride UN2225	98-09-9
531862	BENZIDINE SULPHATE	(1,1'-Biphenyl)-4,4'-diamine, sulphate (1:1)	531-86-2
109795	n-BUTYLMERCAPTAN	n-Butanethiol; Butylmercaptan UN2347	109-79-5
75661	tert-BUTYLMERCAPTAN	tert-Butanethiol; 2-Methyl-2-propanethiol	75-66-1
463581	CARBONYL SULPHIDE		463-58-1
1569693	CYCLOHEXYL-1-MERCAPTAN	Cyclohexanethiol UN3054	1569-69-3
143102	DECYLMERCAPTAN	1-Decanethiol; n-Decylmercaptan; 1-Mercaptodecane	143-10-2
64675	DIETHYLSULPHATE	Diethyl sulphate; DS; Ethyl sulphate; Sulfuric acid, diethyl ester UN1594	64-67-5
77781	DIMETHYLSULPHATE	Dimethyl monosulphate UN1595	77-78-1
112550	DODECYLMERCAPTAN	1-Dodecanethiol; 1-Dodecylmercaptan; Laurylmercaptan; Pennfloat M; Pennfloat S	112-55-0
75081	ETHYLMERCAPTAN	Ethanethiol; Ethyl sulfhydrate; Ethyl thioalcohol; Thioethanol; Thioethyl alcohol UN2363	75-08-1
1639094	n-HEPTYLMERCAPTAN	1-Heptanethiol	1639-09-4
2917262	HEXANETHIOL	Cetylmercaptan; Hexadecanethiol-1; n-Hexadecanethiol; Hexadecylmercaptan	2917-26-2
111319	n-HEXYLMERCAPTAN	1-Hexanethiol	111-31-9
151213	LAURYL SODIUM SULPHATE	Monododecyl sodium sulphate; Sodium dodecyl sulphate; Sodium n-dodecyl sulphate; Sodium dodecyl sulphate; Sodium monolauryl sulphate	151-21-3
60242	2-MERCAPTOETHANOL	1-Ethanol-2-thiol; Ethylene glycol, monothio-; 2-hydroxy-1-ethanethiol; 2-Hydroxyethylmercaptan; Mercaptoethanol; Monothioethyleneglycol; 2-Thioethanol; Thioglycol; Thiomonoglycol UN2966	60-24-2
59518	D,L-METHIONINE	Acimetion; Banthionine; Cynaron; Dyprin; Lobamine; Meonine; Methionine; Metione; Mertionin; Neston	59-51-8
74931	METHYLMERCAPTAN	Methylmercaptan; Methanethiol; Thiomethanol UN1064	74-93-1
67685	METHYL-SULFOXIDE	Dimethyl sulfoxide; Dimethyl sulphoxide; Dimexide; Methane, sulfinylbis-; Methylsulfinylmethane	67-68-5
75183	METHYL-SULPHIDE	Dimethyl sulphide; Dimethyl sulphide; Methyl sulphide; Methylthiomethane; 2-Thiapropane; 2-Thiopropane UN1164	75-18-3
2885009	1-OCTADECANEDIOL	1-Mercaptooctadene; Octadecylmercaptan; Stearylmercaptan	2885-00-9
111886	1-OCTANETHIOL	1-Mercaptooctane; n-Octylmercaptan; Octylthiol; 1-Octylthiol	111-88-6
110667	1-PENTANETHIOL	Amyl hydrosulphide; Amylmercaptan; n-Amylmercaptan; Amyl sulfhydrate; Amyl thioalcohol; Pentylmercaptan	110-66-7
594423	PERCHLOROMETHYLMERCAPTAN	PCM; Trichloromethane sulfenyl chloride; Trichloromethanesulphenyl chloride; Trichloromethylsulfenyl chloride; Trichloromethylsulphenyl chloride UN1670	594-42-3
108985	PHENYLMERCAPTAN	Benzenethiol; Thiophenol UN2337	108-98-5
107039	PROPANETHIOL		107-03-9
25155300	SODIUM DODECYLBENZENESULFONATE		25155-30-0
540727	SODIUM ISOTHIOCYANATE	Sodium rhodanate; Sodium rhodanide; Sodium sulfocyanate; Sodium sulfocyanide; Sodium thiocyanate; Sodium thiocyanide; Thiocyanate sodium	540-72-7
62555	THIOACETAMIDE	Acetothioamide; Ethanethioamide; Thioacetimidic acid	62-55-5
507095	THIOACETIC ACID	Acetylmercaptan; Ethanethioic acid; Ethanethiolic acid; Methanecarbothiolic acid; Thiacetic acid; Thiolacetic acid; Thionoacetic acid UN2436	507-09-5
68111	THIOGLYCOLIC ACID	Glycolic acid, 2-thio-; Mercaptoacetate; Mercaptoacetic acid; 2-Mercaptoacetic acid; 2-Thioglycolic acid; Thiovanic acid UN1940	68-11-1
111488	2,2'-THIODIETHANOL	Bis(b-hydroxyethyl)sulfide; Bis(2-hydroxyethyl)sulfide; Bis(b-hydroxyethyl sulfide; Sulfide, bis(2-hydroxyethyl); Thiodiethylene glycol; Thiodiglycol; b-thiodiglycol	111-48-8
62566	THIOUREA	Isothiourea; Pseudothiourea; Thiocarbamide; Thiocarbonic acid diamide; Beta-thiopseudourea; 2-thiopseudourea; 2-Thiourea; THU	62-56-6
137268	THIRAM	Bis((dimethylamino)carbonothioyl) disulphide; Tetramethyldiurane sulphite; Tetramethylenethiuram disulphide; Tetramethylthioperoxydicarbonic diamide; Tetramethylthiuram; Tetramethylthiuram bisulphide; Tetramethylthiuram disulphide	137-26-8

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:21

Sulphur Compounds, Organic: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
n-BUTYLMERCAPTAN 109-79-5	eyes; skin; resp tract; CNS; thyroid		Inhalation: weakness, confusion, cough, dizziness, headache, nausea, vomiting, shortness of breath Skin: redness, pain Eyes: redness, pain Ingestion: see inhalation	Resp sys; CNS; liver; kidneys; eyes; skin Inh; ing; con	Irrit eyes, skin; musc weak, mal, sweat, nau, vomit, head, conf; in animals: narco, inco, weak; cyan, pulm irrit; liver, kidney damage
tert-BUTYLMERCAPTAN 75-66-1	eyes; skin; resp tract; CNS	skin	Inhalation: cough, dizziness, headache, nausea, vomiting Skin: redness Eyes: redness
CYCLOHEXYLMERCAPTAN 1569-69-3	eyes; skin; resp tract; CNS	skin	Inhalation: cough, dizziness, headache, nausea, unconsciousness, vomiting, weakness Skin: redness Eyes: redness	Eyes; skin; resp sys; CNS Inh; abs; ing; con	Irrit eyes, skin, resp sys; head, dizz, weak, nau, vomit, convuls; cough, wheez, laryngitis, dysp
DECYLMERCAPTAN 143-10-2	eyes; skin; resp tract; CNS	skin	Inhalation: confusion, dizziness, headache, nausea, unconsciousness, weakness Skin: redness Eyes: redness	Eyes; skin; resp sys Inh; abs; ing; con	Irrit eyes, skin, resp sys; conf, dizz, head, drow, nau, vomit, weak, convuls
DODECYLMERCAPTAN 112-55-0	eyes; skin; resp tract; CNS	skin	Inhalation: confusion, cough, dizziness, headache, nausea, shortness of breath, sore throat, unconsciousness, weakness Skin: redness Eyes: redness, pain Ingestion: abdominal pain, dullness, headache, nausea, unconsciousness	Eyes; skin; resp sys; CNS; blood; Inh; con	Irrit eyes, skin, resp sys; cough; dysp, weak, conf, cyan; abdom pain, nau; skin sens
ETHYLMERCAPTAN 75-08-1			Inhalation: drowsiness, nausea, unconsciousness, weakness, tremors Skin: redness Eyes: redness, pain	Resp sys; liver; kidneys; eyes; blood Inh; con	Irrit muc memb; head, nau; in animals: inco, weak; liver, kidney damage; cyan; narco
HEXANETHIOL 2917-26-2	eyes; skin; resp tract; CNS	skin	Inhalation: dizziness, headache, nausea, sore throat, unconsciousness, weakness Skin: redness Eyes: redness	Eyes; skin; resp sys; CNS; blood Inh; abs; ing; con	Irrit eys, skin, resp sys; head, dizz, weak, cyan, nau, convuls
METHYLMERCAPTAN 74-93-1	eyes; skin; resp tract; lungs; CNS; blood; skin		Inhalation: cough, irritant, headache, nausea, shortness of breath, sore throat, unconsciousness Skin: redness, irritant, pain, on contact with liquid: frostbite Eyes: redness, irritant, pain	Resp sys; CNS; eyes; skin; blood Inh; con (liq)	Irrit eyes, skin, resp sys; narco; cyan; convuls; liq: frostbite
1-OCTADECANETHIOL 2885-00-9				Eyes; skin; resp sys; CNS; bloodInh; abs; ing; con	Irrit eyes, skin, resp sys; head; dizz; weak; cyan; nau; convuls
1-OCTANETHIOL 111-88-6				Eyes; skin; resp sys; blood; CNSInh; ing; con	Irrit eyes, skin, nose, throat; weak; cyan; incr respiration; nau; drow; head; vomit
PERCHLOROMETHYLMERCAPTAN 594-42-3	eyes; skin; resp tract; lungs	skin; lungs		Eyes; resp sys; liver; kidneys; skin Inh; abs; ing; con	Irrit eyes, skin, nose, throat; lac; cough, dysp, deep breath pain, coarse rales; vomit; pallor, tacar; acidosis; anuria; liver, kidney damage
PHENYLMERCAPTAN 108-98-5	eyes; skin; resp tract; CNS	skin	Inhalation: cough, headache, laboured breathing Skin: redness, pain Eyes: redness, pain Ingestion: nausea, sore throat	Eyes; skin; resp sys; CNS; kidneys; liver; spleen Inh; abs; ing; con	Irrit eyes, skin, resp sys; derm; cyan; cough, wheez, dysp, pulm edema, pneuitis; head, dizz, CNS depres; nau, vomit; kidney, liver, spleen damage
PROPANETHIOL 107-03-9				Eyes; skin; resp sys; CNS; blood; liver; kidneysInh; ing; con	Irrit eyes, skin, nose, throat, resp sys; head, nau, dizz, cyan; in animals: liver, kidney damage
SODIUM DODECYLBENZENESULFONATE 25155-30-0	eyes; skin; resp tract	skin	Inhalation: cough, laboured breathing Skin: redness Eyes: redness, pain Ingestion: diarrhoea, vomiting
THIOACETAMIDE 62-55-5	eyes; skin; resp tract		Inhalation: cough, laboured breathing, sore throat Skin: redness Eyes: redness, pain, blurred vision Ingestion: burning sensation, sore throat
THIOACETIC ACID 507-09-5	eyes; skin; resp tract; lungs	kidneys	Inhalation: cough, laboured breathing, nausea, sore throat, symptoms may be delayed Skin: burning sensation, pain Eyes: redness, pain, severe deep burns Ingestion: abdominal cramps, burning sensation

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:22

Sulphur Compounds, Organic: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
ANTU 86-88-4		The substance decomposes on heating producing toxic fumes including nitrogen oxides and sulphur oxides • Reacts with strong oxidants causing fire and explosion hazard	6.1
BENZENESULPHONYL CHLORIDE 98-09-9			8
n-BUTYLMERCAPTAN 109-79-5	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on burning or heating, producing highly toxic fumes (sulphur dioxide) • Reacts with acids, bases, alkali metals, and strong oxidants	3
tert-BUTYLMERCAPTAN 75-66-1	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on burning producing highly toxic gases including sulphur oxides • Reacts with strong acids, strong bases, alkali metals, strong reducing agents, strong oxidants
CETYLMERCAPTAN 2917-26-2		The substance decomposes on burning producing highly toxic gases including sulphur oxides • Reacts violently with strong oxidants, acids, reducing agents, alkali metals
CYCLOHEXYLMERCAPTAN 1569-69-3		The substance decomposes on burning producing highly toxic gases including sulphur dioxide • Reacts with strong oxidants, reducing agents, and alkali metals	3
DECYLMERCAPTAN 143-10-2		The substance decomposes on burning producing highly toxic gases including sulphur dioxide • Reacts with strong oxidants and strong bases
DIETHYLSULPHATE 64-67-5		The substance decomposes on heating producing flammable and toxic fumes • The substance is a strong oxidant and reacts with combustible and reducing materials • The substance is a strong reducing agent and reacts with oxidants • The solution in water is a strong acid, it reacts violently with bases and is corrosive	6.1
DIETHYLSULPHIDE 352-93-2			3
DIMETHYLSULPHATE 77-78-1			6.1/ 8
DIMETHYLSULPHIDE 75-18-3	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on heating and on burning producing toxic and corrosive fumes (hydrogen sulphide and sulphur oxides) • Reacts violently with strong oxidants causing fire and explosion hazard	3
DIMETHYLSULPHOXIDE 67-68-5	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on heating above 150 °C or on burning producing toxic fumes • Reacts violently with strong oxidants such as perchlorates
DODECYLMERCAPTAN 112-55-0		The substance decomposes on burning producing highly toxic gases including sulphur dioxide • Reacts violently with strong oxidants and alkali metals
ETHYLMERCAPTAN 75-08-1	The vapour is heavier than air and may travel along the ground; distant ignition possible	On combustion, forms carbon monoxide, sulphur oxides and hydrogen sulphide • The substance is a weak acid • Reacts with oxidants causing fire and explosion hazard • Reacts vigourously with strong acids and bases causing toxic hazard	3
LAURYL SODIUM SULPHATE 151-21-3		On combustion, forms toxic gases • Gives off toxic fumes in a fire
MERCAPTOACETIC ACID 68-11-1			8
2-MERCAPTOETHANOL 60-24-2			8
METHANESULPHONYL CHLORIDE 124-63-0			6.1/ 8
D,L-METHIONINE 59-51-8		The substance decomposes on heating producing sulphur oxides, nitrous oxides • Reacts with strong oxidants
METHYLMERCAPTAN 74-93-1	The gas is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on heating and on burning producing toxic sulphur oxides • Reacts violently with strong oxidants • Reacts with acids to form flammable and toxic gas (hydrogen sulphide)	2.3/ 2.1
1-PENTANETHIOL 110-66-7			3
PERCHLOROMETHYLMERCAPTAN 594-42-3			6.1
PHENYLMERCAPTAN 108-98-5		The substance decomposes on heating producing toxic fumes (sulphur oxides and carbon monoxide) • Reacts with acids to form toxic fumes (sulphur oxides)	6.1/ 3
PROPANETHIOL 107-03-9			3
SODIUM DODECYLBENZENESULPHONATE 25155-30-0		The substance decomposes on heating and on burning producing toxic and irritating fumes (sulphur oxides) • Reacts with acids or acid fumes producing toxic and irritating fumes (sulphur oxides)
SODIUM THIOCYANATE 540-72-7		The substance decomposes on heating and under influence of light producing toxic fumes of sulphur oxides, nitrogen oxides and cyanides • Reacts violently with acids, strong bases and strong oxidants
THIOACETAMIDE 62-55-5		The substance decomposes on burning producing toxic fumes
THIOACETIC ACID 507-09-5	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on burning producing toxic and corrosive fumes (sulphur oxides) • The substance is a medium strong acid and is corrosive • Reacts violently with strong oxidants causing fire and explosion hazard • Reacts slowly with water forming acetic acid and hydrogen sulfide
THIOUREA 62-56-6		The substance decomposes on heating producing toxic fumes of nitrogen oxides and sulphur oxides • acts with sufphydryl-oxidizing agents and forms complexes and adducts with metallic salts and many organic compounds including proteins and certain hydrocarbons • Reacts violently with acrolein, strong acids and strong oxidants
THIRAM 137-26-8	Dust explosion possible if in powder or granular form, mixed with air	The substance decomposes on heating and on burning producing toxic fumes (nitrogen, sulphur oxides) • Reacts with strong oxidants, acids and oxidizable materials	6.1

For UN Class: 1.5 = very insensitive substances which have a mass explosion hazard; 2.1 = flammable gas; 2.3 = toxic gas; 3 = flammable liquid; 4.1 = flammable solid; 4.2 = substance liable to spontaneous combustion; 4.3 = substance which in contact with water emits flammable gases; 5.1 = oxidizing substance; 6.1 = toxic; 7 = radioactive; 8 = corrosive substance

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:24

Sulphur Compounds, Organic: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
n-BUTYLMERCAPTAN 109-79-5	colourless liquid	98.4	-115.7	90.2	sl sol	0.8337	3.1	4.0		2 cc	<225
tert-BUTYLMERCAPTAN 75-66-1	mobile liquid; colourless liquid	64	-0.5	90.2	insol	0.8002	3.1	19.0		-26 cc
CETYLMERCAPTAN 2917-26-2	liquid or solid	184	18		insol	0.84	8.9	10 Pa		135
CYCLOHEXYLMERCAPTAN 1569-69-3	liquid	158	-118	116.2	insol	0.9782	4.00	1.3		43 cc
DECYLMERCAPTAN 143-10-2	colourless liquid	241	-26	174.3	insol	0.84	6.0	<10 Pa
DODECYLMERCAPTAN 112-55-0	water-white to pale yellow liquid; oily colourless liquid	@ 15 mm Hg	-7	202.4	insol	0.8450	7.0	@ 25 °C		1278 oc	230
ETHYLMERCAPTAN 75-08-1	colourless liquid	35	-144.4	62.13	sl sol	0.83907	2.14	589	2.8 ll 18.0 ul	-483	299
n-HEPTYLMERCAPTAN 1639-09-4		177	-43	132.26	insol	0.8427
n-HEXYLMERCAPTAN 111-31-9		151	-81	118.23	insol	0.8424
2-MERCAPTOETHANOL 60-24-2	water-white mobile liquid	@ 742 mm Hg		78.13	sol	1.1143	2.7	1.00 mm Hg
METHYLMERCAPTAN 74-93-1	water-white liquid when below boiling point, or colourless gas	5.9	-123	48.1	sl sol	0.8665	1.66	@ 26.1 °C	3.9 ll 21.8 ul	-18
METHANESULFONYL CHLORIDE 124-63-0	pale yellow liquid	@ 18 mm Hg	-32	114.55	insol	1.4573
OCTADECANETHIOL 2885-00-9	solid	205-209	25			0.8420
n-OCTANETHIOL 111-88-6	water-white liquid	199.1	-49.2	146.30		0.8433				46
1-PENTANETHIOL 110-66-7	liquid	@ 460 mm Hg	-75.7	104.21	insol	0.8421	3.59	@25 °C		18 oc
PERCHLOROMETHYLMERCAPTAN 594-42-3	oily, yellow liquid; yellow to orange-red	147.5		185.88	insol	1.6947	6.414	3 mm Hg
PHENYLMERCAPTAN 108-98-5	water-white liquid; prism-like crystals from petroleum ether	168	-14.8	110.17	insol	1.0766	3.8	@ 18 °C		<55
PROPANETHIOL 107-03-9	colourless, mobile liquid	67-68	-113.3	76.17	sl sol	0.8411 g/ml		@ 25 °C		-20
SODIUM DODECYLBENZENESULFONATE 25155-30-0	white to light yellow flakes, granules, or powder		>300		sol	1.0 for 60% slurry
THIOACETAMIDE 62-55-5	crystals from benzene; colourless leaflets; crystals from alc, plates from ether		116	75.1	v sol
THIOACETIC ACID 507-09-5	yellow liquid	93	<-17	76.1	sl sol	1.064	2.62			18-21
2,2'-THIODIETHANOL 111-48-8		164-166	-10	122.2		1.1819
THIOGLYCOLIC ACID 68-11-1	colourless liquid	@ 20 mm Hg	-16.5	92.1	misc	1.3253		@ 18 °C

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:30

Silicon & Organosilicon Compounds: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
1344952	CALCIUM SILICATE	Calcium hydrosilicate; Calcium monosilicate; Calcium polysilicate; Calcium silicate; Calflo E; Calsil; CS lafarge; Florite R; Marimet 45; Microcal 160; Promaxon P60; Silene WF; Silmos t; Solex; Stabinex NW 7PS; Starlex l; SW 400; Toyofine A	1344-95-2
78104	ETHYL SILICATE	Ethyl orthosilicate; Ethyl silicate; Extrema; Silane, tetraethoxy-; TEOS; Tetraethoxysilane; Tetraethyl orthosilicate; Tetraethyl silicate UN1292	78-10-4
75547	METHYL DICHLOROSILANE	Dichloromethylsilane UN1242	75-54-7
681845	METHYL SILICATE	Methyl orthosilicate; Methyl silicate; Silicic acid, methyl ester of ortho-; Silicic acid, tetramethyl ester; Tetramethoxysilane; Tetramethyl silicate UN2606	681-84-5
75796	METHYL TRICHLOROSILANE	Methylsilicochloroform; Methylsilyl trichloride; Trichloromethylsilane UN1250	75-79-6
9016006	POLYDIMETHYLSILOXANE	Af 72; Af 75; Dimethicone 350; Dow Corning 346; Geon; Good-rite; Gum; Hycar; Latex; Methyl silicone; Polymethylsiloxane	9016-00-6
4109960	SILANE, DICHLORO-		4109-96-0
6834920	SILICIC ACID, DISODIUM SALT	B-W; Crystamet; Disodium metasilicate; Disodium monosilicate; Metso 20; Metso beads, drymet; Silicic acid, disodium salt ; Sodium silicate; Water glass	6834-92-0
Si	SILICON		7440-21-3
SiC	SILICON CARBIDE	Annanox CK; Betarundum; Ultrafine; Carbofrax M; Carbolon; Carbon silicide; Crystar; Crystolon 37; Crystolon 39; Densic c 500	409-21-2
SiO	SILICON MONOXIDE		10477-28-6
7803625	SILICON TETRAHYDRIDE	Flots 100SCO; Monosilane; Silane; Silicane UN2203	7803-62-5
7783611	SILICON TETRAFLUORIDE	Perfluorosilane; Silane, tetrafluoro-; Tetrafluorosilane UN1859	7783-61-1
10026047	TETRACHLOROSILANE	Extrema; Silicon chloride; Silicio(tetracloruro di); Silicon tetrachloride UN1818	10026-04-7
10025782	TRICHLOROSILANE	Silicochloroform; Trichloromonosilane UN1295	10025-78-2
75774	TRIMETHYL CHLOROSILANE	Chlorotrimethylsilane; Silane, trimethylchloro-; Silicane, chlorotrimethyl-; Tl 1163; Trimethylsilyl chloride UN1298	75-77-4

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:32

Silicon & Organosilicon Compounds: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
ETHYL SILICATE 78-10-4				Resp sys; liver; kidneys; blood; skin; eyes Inh; ing; con	Irrit eyes, nose; in animals: lac, dysp, pulm edema; tremor, narco; liver, kidney damage; anemia
METHYL DICHLOROSILANE 75-54-7	eyes; skin; resp tract; lungs
METHYL SILICATE 681-84-5	resp tract; eyes; lungs	kidneys; liver	Inhalation: burning sensation, cough, shortness of breath, sore throat, symptoms may be delayed Eyes: redness, pain, loss of vision	Eyes; resp sys; kidneys Inh; ing; con (vapliq)	Irrit eyes, corn damage (following even short term exposure to vapor); lung, kidney inj; pulm edema
METHYL TRICHLOROSILANE 75-79-6	eyes; skin; resp tract; lungs		Inhalation: corrosive, burning sensation, cough, shortness of breath, unconsciousness, symptoms may be delayed Skin: corrosive, redness, skin burns, pain, blisters Eyes: corrosive, redness, pain, loss of vision, severe deep burns
POLYDIMETHYLSILOXANE 9016-00-6	eyes		Eyes: redness, pain
SILANE, DICHLORO- 4109-96-0	eyes; skin; resp tract; lungs	lungs	Inhalation: burning sensation, cough, laboured breathing, shortness of breath, sore throat Skin: redness, skin burns, burning sensation, pain, blisters Eyes: redness, pain, loss of vision
SILICON TETRAHYDRIDE 7803-62-5	eyes; resp tract; lungs	lungs	Inhalation: burning sensation, cough, laboured breathing, shortness of breath, sore throat, symptoms may be delayed Eyes: redness, pain Ingestion: weakness	Eyes; skin; resp sys; CNS Inh	Irrit eyes, skin, muc memb; nau, head
SILICIC ACID, DISODIUM SALT 6834-92-0	eyes; skin; resp tract; lungs	skin	Inhalation: burning sensation, cough, shortness of breath Skin: redness, serious skin burns, pain, blisters Eyes: redness, pain, blurred vision, severe deep burns Ingestion: burning sensation, diarrhoea, shock or collapse, vomiting, collapse
SILICON TETRAFLUORIDE 7783-61-1	eyes; skin; resp tract; lungs		Inhalation: burning sensation, cough, laboured breathing, shortness of breath, sore throat Skin: redness, skin burns, pain, blisters Eyes: redness, pain, loss of vision, severe deep burns
TETRACHLOROSILANE 10026-04-7	eyes; lungs		Inhalation: burning sensation, cough, laboured breathing, shortness of breath, sore throat Skin: redness, skin burns, pain, blisters Eyes: redness, pain, loss of vision, severe deep burns
TRICHLOROSILANE 10025-78-2	eyes; skin; resp tract; lungs	lungs	Inhalation: burning sensation of the chest, cough, laboured breathing, shortness of breath, sore throat Skin: redness, skin burns, burning sensation, pain, blisters Eyes: redness, pain, loss of vision
TRIMETHYLHLOROSILANE 75-77-4	eyes; skin; resp tract; lungs	skin	Ingestion: Inhalation: burning sensation, cough, laboured breathing Skin: redness, pain, blisters Eyes: redness, pain, severe deep burnsabdominal pain, burning sensation, weakness

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:34

Silicon & Organosilicon Compounds: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
ETHYL SILICATE 78-10-4			3
METHYL DICHLOROSILANE 75-54-7			4.3/ 3/ 8
METHYL TRICHLOROSILANE 75-79-6	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on heating producing hydrogen chloride • Reacts violently with strong oxidants • Reacts violently with water and moisture producing hydrogen chloride, causing fire and explosion hazard • Attacks metals like aluminium and magnesium	3/ 8
POLYDIMETHYLSILOXANE 9016-00-6		The substance decomposes on heating (>150 ºC) producing formaldehyde in small amounts
SILANE, DICHLORO- 4109-96-0	The gas is heavier than air	Reacts violently with water • On contact with air it emits hydrogen chloride
SILICIC ACID, DISODIUM SALT 6834-92-0		The substance is a strong base, it reacts violently with acid and is corrosive in moist air to metals like zinc, aluminium, tin and lead forming a flammable/explosive gas (hydrogen)
SILICON TETRAHYDRIDE 7803-62-5	The gas is heavier than air	The substance may spontaneously ignite on contact with air room temperature
SILICON TETRAFLUORIDE 7783-61-1	The gas is heavier than air	Reacts violently with water • On contact with air it emits hydrogen fluoride	2.3/ 8
SILICON 7440-21-3			4.1
TETRACHLOROSILANE 10026-04-7	The vapour is heavier than air	Reacts violently with water • On contact with air it emits hydrogen chloride and silicic acid
TRICHLOROSILANE 10025-78-2	The vapour is heavier than air and may travel along the ground; distant ignition possible	Reacts violently with water • On contact with air it emits hydrogen chloride • Attacks many metals in presence of water	4.3/ 3/ 8
TRIMETHYLCHLOROSILANE 75-77-4	The vapour is heavier than air and may travel along the ground; distant ignition possible	The substance decomposes on heating producing toxic and corrosive fumes (hydrogen chloride, phosgene) • Reacts violently with water, ketones, alcohol, amines and many other substances, causing explosion hazard • On contact with air it emits corrosive fumes of hydrogen chloride	3/ 8

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:38

Silicon & Organosilicon Compounds: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
CALCIUM SILICATE 1344-95-2	white powder				insol	2.9
ETHYL SILICATE 78-10-4	colourless liquid	168.8	-82.5	208.30	insol	0.933	7.22	1.0 mm Hg	1.3 ll 23 ul	52 oc
METHYL DICHLOROSILANE 75-54-7	colourless liquid	41	-93	115.04	sl sol	@ 27 °C	3.97	46	6.0 ll 55 ul	-9 cc	316
METHYL SILICATE 681-84-5	colourless liquid	121-122	-2	152.25	reacts	1.032	5.3	2.2
METHYL TRICHLOROSILANE 75-79-6	colourless liquid	66.4	-90	149.48	reacts	@ 25 °C	5.17	17.9	5.1 ll ? ul	8	404
POLYDIMETHYLSILOXANE 9016-00-6	clear fluids available in wide range of viscosities				insol	0.97				>200
SILANE, DICHLORO- 4109-96-0	compressed, liquified gas	8.2	-122.0	101.01		1.22	3.484		4.1 ll 99 ul	-307	100 58
SILICIC ACID, DISODIUM SALT 6834-92-0	colourless monoclinic crystals; usually obtained as a glass; also orthorhombic crystals; dustless white granules		1089	122.07	sol	2.614
SILICON CARBIDE 409-21-2	exceedingly hard, green to bluish-black, iridescent, sharp crystals; hexagonal or cubic		2600	40.07	insol	3.23
SILICON MONOXIDE 10477-28-6	amorphous black solid					2.15-2.18
SILICON TETRAHYDRIDE 7803-62-5	gas; colourless	-112	-185	32.13	slowly decomposes	@ 19 °C	1.114		1.37	-22
SILICON TETRAFLUORIDE 7783-61-1	colourless gas	-86	-90.2	104.06		@ -80 °C (liquid)	3.57
SILICON 7440-21-3	black to gray, lustrous, needle-like crystals or octahedral platelets (cubic system); amorphous form is dark brown powder	2355	1410	28.0855	insol		@ 25 °C/4 °C
SODIUM SILICATE 1344-09-8	colourless to white or grayish-white, crystal-like pieces or lumps; lumps of greenish glass; white powders; liquids cloudy or clear				sl sol
TETRACHLOROSILANE 10026-04-7	colourless, clear, mobile liquid	59	-70	169.89		@ 0 °C/4 °C	5.9	@ 5.4 °C
TRICHLOROSILANE 10025-78-2	colourless liquid	31.8	-126.5	135.47		1.3417	4.7	@ -16.4 °C	1.2 ll 90.5 ul	-14 oc	93-104
TRIMETHYLCHLOROSILANE 75-77-4	colourless liquid	57	-57.7	108.66	reacts	@ 25 °C	3.75	26.7	1.8 ll 6 ul	-27

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:46

Phthalates: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
131179	DIALLYL PHTHALATE	1,2-Benzenedicarboxylic acid, di-2-propenyl ester ; Phthalic acid, diallyl ester; o-Phthalic acid, diallyl ester	131-17-9
84742	DIBUTYL PHTHALATE	o-Benzenedicarboxylic acid, dibutyl ester; Benzene-o-dicarboxylic acid di-n-butyl ester; DBP; Dibutyl 1,2-benzenedicarboxylate; Dibutyl phthalate; Di-n-butyl phthalate; n-Butylphthalate; Polycizer dbp	84-74-2
84617	DICYCLOHEXYL PHTHALATE	1,2-Benzenedicarboxylic acid, dicyclohexyl ester; Phthalic acid, dicyclohexyl ester	84-61-7
84662	DIETHYL PHTHALATE	1,2-Benzenedicarboxylic acid, diethyl ester; Ethyl phthalate; Neantine; Palatinol a; Phthalol	84-66-2
3648213	DIHEPTYL PHTHALATE	Di-n-heptyl phthalate; Heptyl phthalate	3648-21-3
26761400	DIISODECYL PHTHALATE	1,2-Benzenedicarboxylic acid, bis(isodecyl)phthalate; DIDP (plasticizer); Diisodecyl phthalate; Phthalic acid, diisodecyl ester	26761-40-0
131113	DIMETHYL PHTHALATE	1,2-Benzenedicarboxylic acid, dimethyl ester; Dimethyl-1,2-benzenedicarboxylate; DMP; Methyl phthalate; Phthalic acid methyl ester	131-11-3
117817	DI-sec-OCTYL PHTHALATE	1,2-Benzenedicarboxylic acid, bis(2-ethylhexyl) ester; Bis(2-ethylhexyl)-1,2-benzenedicarboxylate; Bis(2-ethylhexyl)phthalate; Di(2-ethylhexyl)orthophthalate	117-81-7
84695	PHTHALIC ACID, DIISOBUTYL ESTER	DIBP; Diisobutyl phthalate; Hexaplas M; 1B; Palatinol IC	84-69-5
27554263	PHTHALIC ACID, DIISOOCTYL ESTER	1,2-Benzenedicarboxylic acid, diisooctyl ester; Diisooctyl phthalate; Isooctyl phthalate; Phthalic acid, bis(6-methylheptyl)ester	27554-26-3
27253265	PHTHALIC ACID, DIISOTRIDECYL ESTER	1,2-Benzenedicarboxylic acid, diisotridecyl ester; Diisotridecyl phthalate	27253-26-5
636099	TEREPHTHALIC ACID, DIETHYL ESTER	1,4-Benzenedicarboxylic acid, diethyl ester; Diethyl terephthalate	636-09-9
120616	TEREPHTHALIC ACID, DIMETHYL ESTER	1,4-Benzenedicarboxylic acid, dimethyl 1,4-benzenedicarboxylate; Dimethyl p-phthalate; Dimethyl terephthalate; DMT; Methyl 4-carbomethoxybenzoate; Terephthalic acid methyl ester	120-61-6

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:48

Phthalates: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs Routes of Entry	US NIOSH Symptoms
DIALLYL PHTHALATE 131-17-9	eyes; skin; lungs	liver	Ingestion: diarrhoea, laboured breathing
DIBUTYL PHTHALATE 84-74-2				Eyes; resp sys; GI tractInh; ing; con	Irrit eyes, upper resp sys, stomach
DICYCLOHEXYL PHTHALATE 84-61-7	eyes; skin; resp. tract
DIETHYL PHTHALATE 84-66-2	eyes; skin; CNS		Inhalation: dizziness, dullness Skin: redness Eyes: redness, pain	Eyes; skin; resp sys; CNS; PNS; repro sysInh; inh; con	Irrit eyes, skin, nose, throat; head, dizz, nau; lac; possible polyneur, vestibular dysfunc; pain, numb, weak, spasms in arms & legs; in animals: repro effects
DIISODECYL PHTHALATE 26761-40-0	eyes; skin	liver	Skin: redness Eyes: redness Ingestion: dizziness, nausea, vomiting
DIMETHYL PHTHALATE 131-11-3	eyes; nose; throat	birth defects		Eyes; resp sys; GI tractInh; ing; con	Irrit eyes, upper resp sys; stomach pain
DIMETHYL TEREPHTHALATE 120-61-6	eyes
DI-sec-OCTYL PHTHALATE 117-81-7	eyes; skin; resp. tract; lungs; GI tract	skin	Inhalation: cough, sore throat	eyes; GI tract; resp sys; CNS; liver; repro sys (in animals: liver tumors)Inh; ing; con	Irrit eyes, muc memb; in animals: liver damage; terato effects; (carc)

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Friday, 12 August 2011 00:50

Phthalates: Physical & Chemical Hazards

Chemical Name CAS-Number	Physical	Chemical	UN Class or Division / Subsidiary Risks
DIALLYL PHTHALATE 131-17-9		The substance will polymerize if not inhibited, due to heating or in the presence of a catalyst • On combustion, forms toxic carbon oxides • Reacts with strong oxidants, bases and acids
DIBUTYL PHTHALATE 84-74-2	As a result of flow, agitation, etc, electrostatic charges can be generated	The substance decomposes on burning producing toxic and irritating fumes (phthalic anhydride)
DICYCLOHEXYL PHTHALATE 84-61-7		Reacts with acids, bases
DIETHYL PHTHALATE 84-66-2		The substance decomposes on heating or on burning producing toxic fumes and gases (phthalic anhydride) • Attacks some plastics
DIISODECYL PHTHALATE 26761-40-0		Attacks some forms of plastics
DIISOOCTYL PHTHALATE 27554-26-3		Reacts with strong oxidants
DI-sec-OCTYL PHTALATE 117-81-7		Reacts with strong oxidants, acids, alkalis, and nitrates

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 00:54

Phthalates: Physical & Chemical Properties

Chemical Name CAS-Number	Colour/Form	Boiling Point (°C)	Melting Point (°C)	Molecular Weight	Solubility in Water	Relative Density (water=1)	Relative Vapour Density (air=1)	Vapour Pressure/ (Kpa)	Inflam. Limits	Flash Point (°C)	Auto Ignition Point (°C)
DIALLYL PHTHALATE 131-17-9	nearly colourless oily liquid	160-163	-70	246.26	@ 25 °C	1.120	8.3	@ 150 °C		166
DIBUTYL PHTHALATE 84-74-2	colourless to faint yellow viscous liquid; oily liquid	340	-35	278.34	insol	1.0459	9.58	<0.01	0.5 ll 25.0 ul	157 cc	402
DICYCLOHEXYLPHTHALATE 84-61-7	white, granular solid	@ 4 mm Hg	66	330.4	insol	1.383		@ 150 °C		207
DIETHYL PHTHALATE 84-66-2	colourless, oily liquid	295	-40.5	222.3	insol	1.1175	7.7	@ 75 °C	0.7	161 oc	457
DIISODECYL PHTHALATE 26761-40-0		@ 4 mm Hg	-50	446.7	insol	0.966		@ 200 °C	0.3 ll ? ul	232 oc	402
DIISOOCTYL PHTHALATE 27554-26-3	nearly colourless, viscous liquid	370	-4	390.54	insol	0.986	13.5	<10 Pa		227	393
DIMETHYL PHTALATE 131-11-3	oily-liquid; colourless viscous liquid; pale yellow crystals	283.7	5.5	194.2	insol	1.1905	6.69	<0.01 mm Hg	0.9 ll ? ul	132	490
DIMETHYL TEREPHTHALATE 120-61-6	colourless crystals; needles from ether	288	140	194.2	sl sol	@ 25 °C	5.5	@ 150 °C	0.8 ll 11.8 ul	146 oc	500
DI-sec-OCTYL PHTALATE 117-81-7	light coloured liquid; colourless oily liquid	384	-50	390.54	@ 25 °C	0.9861	16.0	0.001	0.3 ll ? ul	215 oc	390
PHTHALIC ACID, DIHEPTYL ESTER 3648-21-3	colourless liquid	360		362.45	0.01%
PHTHALIC ACID, DIISOBUTYL ESTER 84-69-5	liquid	296.5	-64	278.33	insol	@ 15 °C				185 oc	432

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 01:05

Phosphates, Inorganic & Organic: Chemical Identification

Chemical Formula	Chemical	Synonyms UN Code	CAS-Number
1305993	CALCIUM PHOSPHIDE	Calcium photophor; Photophor UN1360	1305-99-3
107664	DIBUTYL PHOSPHATE	Dibutyl acid phosphate; Dibutyl hydrogen phosphate; Dibutyl phosphate; Dinbutyl phosphate; Phosphoric acid, dibutyl ester	107-66-4
2528361	DIBUTYL PHENYL PHOSPHATE	Dibutyl phenyl phosphate; Phosphoric acid, dibutyl phenyl ester	2528-36-1
2524041	DIETHYLTHIOPHOSPHORYL CHLORIDE	o,o-Diethylphosphorochloridothioate; Diethylchlorothiophosphate; Phosphonothioic acid, chloro, o,o-diethyl ester UN2751	2524-04-1
868859	DIMETHYL HYDROGEN PHOSPHITE	Bis(hydroxymethyl)phosphine oxide; Dimethoxyphosphine oxide; Dimethyl acid phosphite; Dimethyl phosphite; Dimethyl phosphonate; Dimethyl phosphorus acid; Hydrogen dimethyl phosphite; Phosphonic acid, dimethyl ester	868-85-9
680319	HEXAMETHYL PHOSPHORAMIDE	Hexametapol; Hexamethyl phosphoramide; Hexamethylphosphoric acid triamide; Hexamethylphosphoric triamide; Tris(dimethylamino)phosphine oxide; Tris(dimethylamino)phosphorus oxide	680-31-9
638211	PHENYLPHOSPHINE	Phenylphosphine	638-21-1
7803512	PHOSPHINE	Gas-ex-B; Hydrogen phosphide; Phosphorus trihydride UN2199	7803-51-2
7723140	PHOSPHORUS (red)	Phosphorus, amorphous UN1338	7723-14-0
7719122	PHOSPHORUS-CHLORIDE	Phosphorus chloride; Phosphorus trichloride; Trichlorophosphine UN1809	7719-12-2
1314563	PHOSPHORUS-OXIDE	Diphosphorus pentoxide; Phosphorus(V) oxide; Phosphorus pentaoxide; Phosphorus pentoxide; Phosphorus pentoxide UN1807	1314-56-3
10025873	PHOSPHORUS OXYCHLORIDE	Phosphorus oxytrichloride; Phosphoryl chloride UN1810	10025-87-3
10026138	PHOSPHORUS PENTACHLORIDE	Phosphoric chloride; Phosphorus perchloride UN1806	10026-13-8
1314803	PHOSPHORUS PENTASULFIDE	Phosphoric sulfide; Phosphorus persulfide; Sulphur phosphide; Thiophosphoric anhydride UN1340	1314-80-3
1314858	TETRAPHOSPHORUS TRISULPHIDE		1314-85-8
3982910	THIOPHOSPHORYL CHLORIDE	Phosphorothioic trichloride; Phosphorothionic trichloride; Phosphorus sulfochloride; Phosphorus thiochloride; Thiophosphoric trichloride; Thiophosphoryl trichloride UN1837	3982-91-0
1330785	TRICRESYL PHOSPHATE	Flexol plasticizer TCP; Phosphoric acid, tritolyl ester; Tris(tolyloxy)phosphine oxide; Tritolyl phosphate UN2574	1330-78-5
78308	TRI-o-CRESYL PHOSPHATE	o-Cresyl phosphate; Phosphoric acid, tri-o-tolyl ester; TOCP; TOFK; o-Tolyl phosphate; TOTP; Tricresyl phosphate; Triocresyl phosphate; Tri-2-methylphenyl phosphate; Tris(o-cresyl)phosphate; Tris(o-methylphenyl)phosphate; Tris(o-tolyl)phosphate; Tri-o-tolyl phosphate; Tri-2-tolyl phosphate	78-30-8
78400	TRIETHYL PHOSPHATE	Ethyl phosphate; Phosphoric acid, triethyl ester; TEP	78-40-0
7320345	TETRAPOTASSIUM PYROPHOSPHATE	Diphosphoric acid, tetrapotassium salt; Potassium pyrophosphate; Tetrapotassium diphosphorate; TKPP	7320-34-5
7722885	TETRASODIUM PYROPHOSPHATE	Anhydrous tetrasodium pyrophosphate; Phosphotex; Pyrophosphate; Sodium pyrophosphate; Tetrasodium diphosphate; Tetrasodium pyrophosphate, anhydrous; TSPP	7722-88-5
126727	TRIS(2,3-DIBROMOPROPYL) PHOSPHATE	2,3-Dibromo1propanol phosphate; (2,3-Dibromopropyl) phosphate; Fyrol HB32; NCI-C03270; Phosphoric acid, tris(2,3-dibromopropyl) ester; 1-Propanol, 2,3-dibromo, phosphate (3:1); RCRA Waste number U235; TDBPP; T 23P; Tris; TrisBP; Tris(dibromopropyl)phosphate; Tris(2,3-dibromopropyl) phosphoric acid ester; Tris (flame retardant); USAF DO41; Zetifex ZN	126-72-7
78422	TRIS(2-ETHYLHEXYL) PHOSPHATE	2-Ethyl-1-hexanol phosphate; 1-Hexanol, 2-ethyl-, phosphate; Phosphoric acid, tris(2-ethylhexyl) ester; TOF; Triethylhexyl phosphate; Trioctyl phosphate	78-42-2
512561	TRIMETHYL PHOSPHATE	Methyl phosphate; NCI-C03781; Phosphoric acid, trimethyl ester; TMP; o,o,o-Trimethyl phosphate	512-56-1
126738	TRIBUTYL PHOSPHATE	Butyl phosphate, tri; Tbp; Tributyl phosphate; Trinbutyl phosphate	126-73-8
122521	TRIETHYL PHOSPHITE	Phosphorus acid, triethyl ester UN2323	122-52-1
121459	TRIMETHYL PHOSPHITE	Methyl phosphite; Trimethoxyphosphine; Phosphorus acid, trimethyl ester UN2329	121-45-9
115866	TRIPHENYL PHOSPHATE	Celluflex TPP; TPP	115-86-6
101020	TRIPHENYL PHOSPHITE		101-02-0
603350	TRIPHENYL PHOSPHINE		603-35-0

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Published in 104. Guide to Chemicals

Friday, 12 August 2011 01:07

Phosphates, Inorganic & Organic: Health Hazards

Chemical Name CAS-Number	ICSC Short-Term Exposure	ICSC Long-Term Exposure	ICSC Routes of Exposure and Symptoms	US NIOSH Target Organs & Routes of Entry	US NIOSH Symptoms
DIBUTYL PHOSPHATE 107-66-4				Resp sys; skin; eyes Inh; ing; con	Irrit eyes, skin, resp sys; head
DIETHYLTHIOPHOSPHORYL CHLORIDE 2524-04-1	eyes; skin; resp tract; lungs		Inhalation: burning sensation, confusion, cough, dizziness, headache, nausea, shortness of breath, sore throat, unconsciousness, vomiting, weakness, symptoms may be delayed Skin: may be absorbed, redness, burning sensation, pain Eyes: vapour will be absorbed, redness, pain, blurred vision, loss of vision, severe deep burns Ingestion: confusion, diarrhoea, headache, nausea, vomiting
PHOSPHINE 7803-51-2	eyes; skin; resp tract; lungs; CNS; blood; liver; kidneys; heart		Inhalation: burning sensation, diarrhoea, dizziness, dullness, headache, tremors, laboured breathing, nausea, sore throat Skin: redness, pain, on contact with liquid: frostbite Eyes: in case of frostbite: redness, pain	Resp sys Inh; con (liq)	Nau, vomit, abdom pain, diarr; thirst; chest tight, dysp; musc pain, chills; stupor or syncope; pulm edema; liq: frostbite
PHOSPHORUS 7723-14-0	eyes; skin; resp tract; lungs; liver; kidneys	bone	Inhalation: burning sensation, unconsciousness, symptoms may be delayed Skin: skin burns, pain Eyes: pain, loss of vision, severe deep burns Ingestion: abdominal cramps, unconsciousness	Resp sys; liver; kidneys; jaw; teeth; blood; eyes; skin Inh; ing; con	Irrit eyes, resp tract; eye, skin burns; abdom pain, nau, jaun; anemia; cachexia; dental pain, salv, jaw pain, swell
PHOSPHORUS PENTACHLORIDE 10026-13-8			Inhalation: burning sensation, cough, shortness of breath, vomiting, symptoms may be delayed Skin: may be absorbed, roughness, serious skin burns Eyes: pain, severe deep burns Ingestion: abdominal cramps, abdominal pain, burning sensation, weakness	Resp sys; eyes; skin Inh; ing; con	Irrit eyes, skin, resp sys; bron; derm
PHOSPHORUS PENTASULFIDE 1314-80-3				Resp sys; CNS; eyes; skin Inh; ing; con	Irrit eyes, skin, resp sys; apnea, coma, convuls; conj pain, lac, photo, kerato-conj, corn vesic; dizz; head; ftg; irrity, insom; GI dist
PHOSPHORUS PENTOXIDE 1314-56-3	eyes; skin; resp tract; lungs		Inhalation: burning sensation, cough, shortness of breath Skin: redness, skin burns, pain Eyes: redness, pain, severe deep burns Ingestion: abdominal pain, diarrhoea, nausea, vomiting
PHOSPHORUS TRICHLORIDE 7719-12-2			Inhalation: burning sensation, cough, diarrhoea, dizziness, headache, shortness of breath, sore throat, vomiting Skin: serious skin burns, pain, blisters Eyes: redness, blurred vision, severe deep burns Ingestion: burning sensation, sore throat ,	Resp sys; eyes; skin Inh; ing; con	Irrit eyes, skin, nose, throat; pulm edema; eye, skin burns
TETRAPOTASSIUM PYROPHOSPHATE 7320-34-5	eyes; skin; resp tract; lungs		Inhalation: burning sensation, cough, laboured breathing Skin: redness, pain, blisters Eyes: redness, pain, severe deep burns Ingestion: burning sensation, sore throat, abdominal cramps, weakness
TETRASODIUM PYROPHOSPHATE 7722-88-5	eyes; skin; resp tract		Inhalation: burning sensation, cough Skin: redness, pain Eyes: redness, pain Ingestion: nausea, vomiting, diarrhoea	Eyes; skin; resp sys Inh; ing; con	Irrit eyes, skin, nose, throat; derm
THIOPHOSPHORYL CHLORIDE 3982-91-0	eyes; skin; resp tract; lungs	lungs	Inhalation: burning sensation, confusion, cough, headache, wheezing, laboured breathing, shortness of breath, sore throat, unconsciousness, vomiting, weakness, symptoms may be delayed Skin: may be absorbed, skin burns, pain Eyes: pain, loss of vision, severe deep burns Ingestion: abdominal cramps, abdominal pain, burning sensation, confusion, cough, headache, nausea, shortness of breath, sore throat, unconsciousness, vomiting
TRIBUTYL PHOSPHATE 126-73-8	eyes; skin; resp tract; lungs; CNS	skin; blood	Inhalation: dizziness, headache, convulsions, laboured breathing, nausea, sore throat Skin: may be absorbed, redness, roughness, burning sensation Eyes: redness, pain Ingestion: abdominal cramps, diarrhoea, laboured breathing, nausea, unconsciousness, vomiting, weakness, hypersalivation	Resp sys; skin; eyes Inh; ing; con	Irrit eyes, skin, resp sys; head; nau
TRI-o-CRESYL PHOSPHATE 78-30-8			Inhalation: headache, nausea, vomiting, muscular pain, symptoms may be delayed Skin: may be absorbed, redness, pain Ingestion: abdominal pain, nausea, vomiting	PNS; CNS Inh; abs; ing; con	GI dist; peri neur; cramps in calves; pares in feet or hands; weak feet, wrist drop, para
TRIETHYL PHOSPHITE 122-52-1	eyes; skin; resp tract; lungs; CNS		Inhalation: burning sensation, headache, nausea, sore throat, symptoms may be delayed Skin: may be absorbed, redness Eyes: redness, pain Ingestion: abdominal pain
TRIMETHYL PHOSPHATE 512-56-1	CNS	CNS; genes
TRIPHENYL PHOSPHATE 115-86-6				Blood; PNS Inh; ing	Minor changes in blood enzymes; in animals: musc weak, para
TRIPHENYLPHOSPHINE 603-35-0	eyes; skin; resp tract		Inhalation: cough, sore throat Skin: redness Eyes: redness, pain Ingestion: cough
TRIPHENYL PHOSPHITE 101-02-0	eyes; skin; resp tract; CNS		Inhalation: burning sensation, cough, irritant unconsciousness Skin: redness, pain Eyes: redness, pain
TRIS(2-ETHYLHEXYL PHOSPHATE) 78-42-2	skin		Skin: redness Eyes: redness

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Ethers Tables:

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Halogenated Saturated Hydrocarbons Tables:

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